Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons

Patent ·
OSTI ID:1067879
 [1];  [1];  [1]
  1. Idaho Falls, ID
+ Show Author Affiliations
Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC07-05ID14517
Assignee:
Battelle Energy Alliance, LLC (Idaho Falls, ID)
Patent Number(s):
8,226,909
Application Number:
12/970,689
OSTI ID:
1067879
Country of Publication:
United States
Language:
English

References (46)

Methanol Synthesis from CO and CO 2 Hydrogenations over Supported Palladium Catalysts journal June 2002
Fischer–Tropsch synthesis on RuTi intermetallic compound catalyst journal January 2005
Zeolites and zeolite-like materials journal January 1986
The promotions of MnO and K2O to Fe/silicalite-2 catalyst for the production of light alkenes from CO2 hydrogenation journal October 1998
Improved activity of FeCu catalysts by physical mixing with zeolites for the hydrogenation of carbon dioxide journal June 1997
Hydrogenation of carbon dioxide over Fe–Cu–Na/zeolite composite catalysts: Na migration via solid–solid reaction and its effects on the catalytic activity journal December 1998
Carbon Nanotube Templated Growth of Mesoporous Zeolite Single Crystals journal December 2001
Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction journal September 2001
Mono-sized single-wall carbon nanotubes formed in channels of AlPO4-5 single crystal journal October 1998
Hydrogenation of carbon dioxide over copper-pyrochlore/zeolite composite catalysts journal May 1996
Mesoporous HMS molecular sieves supported cobalt catalysts for Fischer–Tropsch synthesis journal September 2001
Towards a chemical understanding of the Fischer–Tropsch reaction: alkene formation journal October 1999
Direct synthesis of middle iso-paraffins from synthesis gas on hybrid catalysts journal June 2004
Support effects in cobalt-based fischer-tropsch catalysis journal March 1993
Zeolite-Catalyzed Hydrocarbon Formation from Methanol: Density Functional Simulations journal April 2002
Active centres for synthesis gas reactions journal February 1992
Comparative study of Fischer–Tropsch synthesis with H2/CO and H2/CO2 syngas using Fe- and Co-based catalysts journal October 1999
Cobalt-modified Cu$z.sbnd;Zn$z.sbnd;Cr catalysts in the synthesis of methanol journal June 1992
Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids journal October 1984
Characterization of Catalytic Surfaces by Isotopic-Transient Kinetics during Steady-State Reaction journal May 1995
Catalytic reduction of carbon dioxide. The effects of catalysts and reductants journal June 1995
Crystals in CrystalsNanocrystals within Mesoporous Zeolite Single Crystals journal June 2005
Change of catalytic properties of FeZnO/zeolite composite catalyst in the hydrogenation of carbon dioxide journal June 1997
Transition-Metal Ions in Aluminophosphate and Silicoaluminophosphate Molecular Sieves:  Location, Interaction with Adsorbates and Catalytic Properties journal March 1999
Ultrasound as a Tool to Synthesize Nano-Sized Silica–Alumina Catalysts with Controlled Mesoporous Distribution by a Novel Sol–Gel Process journal March 2002
Methanol-to-hydrocarbons: catalytic materials and their behavior journal June 1999
Methanol Synthesis from CO 2 Under Atmospheric Pressure over Supported Pd Catalysts journal July 2004
Liquid-phase synthesis of methanol from CO2/H2 over ultrafine CuB catalysts journal January 2001
Mesopore-Modified Zeolites:  Preparation, Characterization, and Applications journal March 2006
Recent Advances in Catalysts for Methanol Synthesis via Hydrogenation of CO and CO 2 journal December 2003
The Hydrothermal Synthesis of Zeolites: History and Development from the Earliest Days to the Present Time journal March 2003
Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors journal November 2001
Three-component hybrid catalyst for direct synthesis of isoparaffin via modified Fischer–Tropsch synthesis journal March 2003
Synthesis of methanol from carbon monoxide and hydrogen over a copper-zinc oxide-alumina catalyst journal March 1985
Pd-Modified Cu?Zn Catalysts for Methanol Synthesis from CO2/H2 Mixtures: Catalytic Structures and Performance journal September 2002
Fischer-Tropsch activity in NiOThO2 catalysts journal February 1986
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism journal October 1992
Catalytic conversion of carbon dioxide into hydrocarbons over iron supported on alkali ion-exchanged Y-zeolite catalysts journal April 1999
Development of Cu/ZnO-based high performance catalysts for methanol synthesis by CO2 hydrogenation journal June 1995
Direct synthesis of middle iso-paraffins from synthesis gas journal August 2003
Rational Design of Nanostructured Copper–Zinc Oxide Catalysts for the Steam Reforming of Methanol journal January 2004
Direct synthesis of isoalkanes through Fischer-Tropsch reaction on hybrid catalysts journal March 1994
Structure and function of real catalysts journal November 1984
Carbon monoxide hydrogenation over molybdenum and tungsten carbides journal September 2003
Ship-in-bottle synthesis and catalytic performances of platinum carbonyl clusters, nanowires, and nanoparticles in micro- and mesoporous materials journal March 2001
CO and CO2 hydrogenation study on supported cobalt Fischer–Tropsch synthesis catalysts journal January 2002

Similar Records

Related Subjects

47 OTHER INSTRUMENTATION