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Title: An Organometallic Future in Green and Energy Chemistry?

Abstract

The title topic is reviewed with selected examples taken from recent work, such as: the 'hydrogen borrowing' amine alkylation by alcohols; the dehydrogenative coupling of amine and alcohol to give amide; Ru complexes as solar cell photosensitizers; Ir organometallics as water oxidation catalyst precursors and as OLED emitters; as well as recent hydrogen storage strategies involving catalytic dehydrogenation of ammonia-borane and of organic heterocycles.

Authors:
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC); Center for Catalytic Hydrocarbon Functionalization (CCHF)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1064811
DOE Contract Number:
SC0001298
Resource Type:
Journal Article
Resource Relation:
Journal Name: Organometallics; Journal Volume: 30; Journal Issue: 1; Related Information: CCHF partners with University of Virginia (lead); Brigham Young University; California Institute of Technology; Colorado School of Mines; University of Maryland; University of North Carolina, Chapel Hill; University of North Texas; Princeton University; The Scripps Research Institute; Yale University
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Crabtree, Robert H. An Organometallic Future in Green and Energy Chemistry?. United States: N. p., 2011. Web. doi:10.1021/om1009439.
Crabtree, Robert H. An Organometallic Future in Green and Energy Chemistry?. United States. doi:10.1021/om1009439.
Crabtree, Robert H. Mon . "An Organometallic Future in Green and Energy Chemistry?". United States. doi:10.1021/om1009439.
@article{osti_1064811,
title = {An Organometallic Future in Green and Energy Chemistry?},
author = {Crabtree, Robert H},
abstractNote = {The title topic is reviewed with selected examples taken from recent work, such as: the 'hydrogen borrowing' amine alkylation by alcohols; the dehydrogenative coupling of amine and alcohol to give amide; Ru complexes as solar cell photosensitizers; Ir organometallics as water oxidation catalyst precursors and as OLED emitters; as well as recent hydrogen storage strategies involving catalytic dehydrogenation of ammonia-borane and of organic heterocycles.},
doi = {10.1021/om1009439},
journal = {Organometallics},
number = 1,
volume = 30,
place = {United States},
year = {Mon Jan 10 00:00:00 EST 2011},
month = {Mon Jan 10 00:00:00 EST 2011}
}