A Case for Molecular Recognition in Nuclear Separations: Sulfate Separation from Nuclear Wastes

Journal Article · Tue Jan 01 00:00:00 EST 2013 · Inorganic Chemistry

DOI:https://doi.org/10.1021/ic3016832· OSTI ID:1055546

Moyer, Bruce A ^[1]; Custelcean, Radu ^[1]; Hay, Benjamin ^[1]; Sessler, Jonathan L. ^[2]; Bowman-James, Kristin ^[3]; Day, Victor W. ^[3]; Kang, S. O. ^[3]

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1. ORNL
2. University of Texas
3. University of Kansas

In this paper, we present the case for molecular-recognition approaches for sulfate removal from radioactive wastes via the use of anion-sequestering systems selective for sulfate, using either liquid liquid extraction or crystallization. Potential benefits of removing sulfate from the waste include improved vitrification of the waste, reduced waste-form volume, and higher waste-form performance, all of which lead to potential cleanup schedule acceleration and cost savings. The need for sulfate removal from radioactive waste, especially legacy tank wastes stored at the Hanford site, is reviewed in detail and primarily relates to the low solubility of sulfate in borosilicate glass. Traditional methods applicable to the separation of sulfate from radioactive wastes are also reviewed, with the finding that currently no technology has been identified and successfully demonstrated to meet this need. Fundamental research in the authors laboratories targeting sulfate as an important representative of the class of oxoanions is based on the hypothesis that designed receptors may provide the needed ability to recognize sulfate under highly competitive conditions, in particular where the nitrate anion concentration is high. Receptors that have been shown to have promising affinity for sulfate, either in extraction or in crystallization experiments, include hexaurea tripods, tetraamide macrocycles, cyclo[8]pyrroles, calixpyrroles, and self-assembled urea-lined cages. Good sulfate selectivity observed in the laboratory provides experimental support for the proposed molecular-recognition approach.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1055546
• Journal Information: Inorganic Chemistry, Vol. 52, Issue 7; ISSN 0020--1669
• Country of Publication: United States
• Language: English