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Title: Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
OSTI Identifier:
1050109
Report Number(s):
NREL/JA-5200-55919
Journal ID: ISSN 0002-7863; JACSAT; TRN: US201218%%480
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Journal Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 134; Journal Issue: 24; Journal ID: ISSN 0002-7863
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; HYDROGEN; SPACERS; SURFACE AREA; hybrid materials; ultralow densities; chemical catalysis

Citation Formats

Farha, Omar K., Wilmer, Christopher E., Eryazici, Ibrahim, Hauser, Brad G., Parilla, Philip A., Oneill, Kevin, Sarjeant, Amy A., Nguyen, SonBinh T., Snurr, Randall Q., and Hupp, Joseph T. Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?. United States: N. p., 2012. Web. doi:10.1021/ja302623w.
Farha, Omar K., Wilmer, Christopher E., Eryazici, Ibrahim, Hauser, Brad G., Parilla, Philip A., Oneill, Kevin, Sarjeant, Amy A., Nguyen, SonBinh T., Snurr, Randall Q., & Hupp, Joseph T. Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?. United States. https://doi.org/10.1021/ja302623w
Farha, Omar K., Wilmer, Christopher E., Eryazici, Ibrahim, Hauser, Brad G., Parilla, Philip A., Oneill, Kevin, Sarjeant, Amy A., Nguyen, SonBinh T., Snurr, Randall Q., and Hupp, Joseph T. 2012. "Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?". United States. https://doi.org/10.1021/ja302623w.
@article{osti_1050109,
title = {Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?},
author = {Farha, Omar K. and Wilmer, Christopher E. and Eryazici, Ibrahim and Hauser, Brad G. and Parilla, Philip A. and Oneill, Kevin and Sarjeant, Amy A. and Nguyen, SonBinh T. and Snurr, Randall Q. and Hupp, Joseph T.},
abstractNote = {We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.},
doi = {10.1021/ja302623w},
url = {https://www.osti.gov/biblio/1050109}, journal = {Journal of the American Chemical Society},
issn = {0002-7863},
number = 24,
volume = 134,
place = {United States},
year = {Wed Jun 20 00:00:00 EDT 2012},
month = {Wed Jun 20 00:00:00 EDT 2012}
}