Generalized Hydrodynamic Treatment of the Interplay between Restricted Transport and Catalytic Reactions in Nanoporous Materials
Journal Article
·
· Physical Review Letters
Behavior of catalytic reactions in narrow pores is controlled by a delicate interplay between fluctuations in adsorption-desorption at pore openings, restricted diffusion, and reaction. This behavior is captured by a generalized hydrodynamic formulation of appropriate reaction-diffusion equations (RDE). These RDE incorporate an unconventional description of chemical diffusion in mixed-component quasi-single-file systems based on a refined picture of tracer diffusion for finite-length pores. The RDE elucidate the nonexponential decay of the steady-state reactant concentration into the pore and the non-mean-field scaling of the reactant penetration depth.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC02-07CH11358
- OSTI ID:
- 1045917
- Report Number(s):
- IS-J 7715
- Journal Information:
- Physical Review Letters, Vol. 108, Issue 22
- Country of Publication:
- United States
- Language:
- English
Similar Records
Modeling of the interplay between single-file diffusion and conversion reaction in mesoporous systems
Catalytic conversion in nanoporous materials: Concentration oscillations and spatial correlations due to inhibited transport and intermolecular interactions
Interplay between inhibited transport and reaction in nanoporous materials
Thesis/Dissertation
·
Fri Jan 11 00:00:00 EST 2013
·
OSTI ID:1045917
Catalytic conversion in nanoporous materials: Concentration oscillations and spatial correlations due to inhibited transport and intermolecular interactions
Journal Article
·
Thu Nov 03 00:00:00 EDT 2016
· Journal of Chemical Physics
·
OSTI ID:1045917
Interplay between inhibited transport and reaction in nanoporous materials
Thesis/Dissertation
·
Tue Jan 01 00:00:00 EST 2013
·
OSTI ID:1045917