Layered (2-D) Structure of [Ru2(O2CMe)4]2[Ni(CN)4] Determined via Rietveld Refinement of Synchrotron Powder Diffraction Data
Journal Article
·
· Inorganica Chimica Acta
OSTI ID:1042188
Reaction of [Ru{sub 2}(O{sub 2}CMe){sub 4}]Cl and K{sub 2}[Ni(CN){sub 4}] forms [Ru{sub 2}(O{sub 2}CMe){sub 4}]{sub 2}[Ni(CN){sub 4}] with the targeted layered structure possessing Ru-N{triple_bond}C-Ni linkages, albeit strained, with Ru-N{triple_bond}C and Ni-C{triple_bond}N angles in the range of 147-167{sup o}. The magnetic properties of [Ru{sub 2}(O{sub 2}CMe){sub 4}]{sub 2}[Ni(CN){sub 4}] can be fit to a zero-field splitting model with D/k{sub B} = 95 K (66 cm{sup -1}).
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE SC OFFICE OF SCIENCE (SC)
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 1042188
- Report Number(s):
- BNL-97866-2012-JA; ICHAA3; TRN: US201212%%599
- Journal Information:
- Inorganica Chimica Acta, Vol. 364, Issue 1; ISSN 0020-1693
- Country of Publication:
- United States
- Language:
- English
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