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Title: Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering

Abstract

The mechanism behind the multistep synthesis of two metal-organic frameworks sharing the same metal and organic precursors was revealed by in-situ time-resolved small- and wide-angle X-ray scattering. Key factors governing the crystal assembly could be established (see picture: C gray, H white, N blue, O red, Al yellow, Cl green), including solvent, temperature, and precursor concentration.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE SC OFFICE OF SCIENCE (SC)
OSTI Identifier:
1041598
Report Number(s):
BNL-96709-2011-JA
Journal ID: ISSN 1433-7851; R&D Project: LS001; TRN: US201212%%16
DOE Contract Number:  
DE-AC02-98CH10886
Resource Type:
Journal Article
Journal Name:
Angewandte Chemie International Edition
Additional Journal Information:
Journal Volume: 50; Journal Issue: 41; Journal ID: ISSN 1433-7851
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CRYSTALLIZATION; KINETICS; PRECURSOR; SCATTERING; SMALL ANGLE SCATTERING; SYNTHESIS

Citation Formats

Stavitski, E, M, Goesten, Juan-Alcaniz, J, Martinez-Joaristi, A, Serra-Crespo, P, Petukhov, A, Gascon, J, and Kapteijn, F. Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering. United States: N. p., 2011. Web. doi:10.1002/anie.201101757.
Stavitski, E, M, Goesten, Juan-Alcaniz, J, Martinez-Joaristi, A, Serra-Crespo, P, Petukhov, A, Gascon, J, & Kapteijn, F. Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering. United States. https://doi.org/10.1002/anie.201101757
Stavitski, E, M, Goesten, Juan-Alcaniz, J, Martinez-Joaristi, A, Serra-Crespo, P, Petukhov, A, Gascon, J, and Kapteijn, F. 2011. "Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering". United States. https://doi.org/10.1002/anie.201101757.
@article{osti_1041598,
title = {Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering},
author = {Stavitski, E and M, Goesten and Juan-Alcaniz, J and Martinez-Joaristi, A and Serra-Crespo, P and Petukhov, A and Gascon, J and Kapteijn, F},
abstractNote = {The mechanism behind the multistep synthesis of two metal-organic frameworks sharing the same metal and organic precursors was revealed by in-situ time-resolved small- and wide-angle X-ray scattering. Key factors governing the crystal assembly could be established (see picture: C gray, H white, N blue, O red, Al yellow, Cl green), including solvent, temperature, and precursor concentration.},
doi = {10.1002/anie.201101757},
url = {https://www.osti.gov/biblio/1041598}, journal = {Angewandte Chemie International Edition},
issn = {1433-7851},
number = 41,
volume = 50,
place = {United States},
year = {Thu Jul 14 00:00:00 EDT 2011},
month = {Thu Jul 14 00:00:00 EDT 2011}
}