Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds

Peterman, Dean R; Meikrantz, David H; Law, Jack D; Riddle, Catherine L; Todd, Terry A; Greenhalgh, Mitchell R; Tillotson, Richard D; Bartsch, Richard A; Moyer, Bruce A; Delmau, Laetitia H; Bonnesen, Peter V

Title: Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds

Patent · Tue Apr 17 00:00:00 EDT 2012

OSTI ID:1040866

Peterman, Dean R ^[1]; Meikrantz, David H ^[1]; Law, Jack D ^[2]; Riddle, Catherine L ^[1]; Todd, Terry A ^[3]; Greenhalgh, Mitchell R ^[4]; Tillotson, Richard D ^[5]; Bartsch, Richard A ^[6]; Moyer, Bruce A ^[7]; Delmau, Laetitia H ^[7]; Bonnesen, Peter V ^[8]

Idaho Falls, ID
Pocatello, ID
Firth, ID
Iona, ID
Moore, ID
Lubbock, TX
Oak Ridge, TN
Knoxville, TN

A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4',4',(5')-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC07-99ID13727; AC07-05ID14517

Assignee:: Battelle Energy Alliance, LLC (Idaho Falls, ID)

Patent Number(s):: 8,158,088

Application Number:: 12/268,189

OSTI ID:: 1040866

Country of Publication:: United States

Language:: English

References (34)

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