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Title: Functionalized sorbent for chemical separations and sequential forming process

Patent ·
OSTI ID:1039697

A highly functionalized sorbent and sequential process for making are disclosed. The sorbent includes organic short-length amino silanes and organic oligomeric polyfunctional amino silanes that are dispersed within pores of a porous support that form a 3-dimensional structure containing highly functionalized active binding sites for sorption of analytes.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
8,138,117
Application Number:
US patent applicaiton 12/555,374
OSTI ID:
1039697
Country of Publication:
United States
Language:
English

References (12)

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Adsorption capacities of carbon dioxide, oxygen, nitrogen and methane on carbon molecular basket derived from polyethyleneimine impregnation on microporous palm shell activated carbon journal September 2008
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Periodic Mesoporous Silica-Supported Recyclable Rhodium-Complexed Dendrimer Catalysts journal October 2004
Polyethyleneimine and macrocyclic polyamine silica gels acting as carbon dioxide absorbents journal January 1992
Engineering Nanospaces: Iterative Synthesis of Melamine-Based Dendrimers on Amine-Functionalized SBA-15 Leading to Complex Hybrids with Controllable Chemistry and Porosity journal June 2004
Polyethyleneimine impregnation on activated carbon: Effects of impregnation amount and molecular number on textural characteristics and metal adsorption capacities journal December 2008
Diethylenetriamine[propyl(silyl)]-Functionalized (DT) Mesoporous Silicas as CO 2 Adsorbents journal April 2006
Polyamine-functionalized mesoporous silicas: Preparation, structural analysis and oxyanion adsorption journal October 2005
Thermal and Chemical Stability of Regenerable Solid Amine Sorbent for CO 2 Capture journal July 2006
Method to Double the Surface Concentration and Control the Orientation of Adsorbed (3-Aminopropyl)dimethylethoxysilane on Silica Powders and Glass Slides journal August 2002
Wet-Chemical Analysis of Surface Concentration of Accessible Groups on Different Amino-Functionalized Mesoporous SBA-15 Silicas journal October 2007