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Title: Selective Adsorption of CO2 from Light Gas Mixtures Using a Structurally Dynamic Porous Coordination Polymer**

Journal Article · · Angewandte Chemie International Edition
OSTI ID:1036463

The selective adsorption of CO{sub 2} from mixtures with N{sub 2}, CH{sub 4}, and N{sub 2}O in a dynamic porous coordination polymer (see monomer structure) was evaluated by ATR-FTIR spectroscopy, GC, and SANS. All three techniques indicate highly selective adsorption of CO{sub 2} from CO{sub 2}/CH{sub 4} and CO{sub 2}/N{sub 2} mixtures at 30 C, with no selectivity observed for the CO{sub 2}/N{sub 2}O system.

Research Organization:
National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research; Federal Energy Technology Center-Pittsburgh (FETC-PGH), Pittsburgh, PA (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
OSTI ID:
1036463
Report Number(s):
NETL-PUB-272; TRN: US201206%%327
Journal Information:
Angewandte Chemie International Edition, Vol. 50, Issue 46; ISSN 1433-7851
Country of Publication:
United States
Language:
English