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Title: Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing

Abstract

The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is dependent on the dimension of SBB's. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which can be added on the list of invariant rod packings.

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1027176
Report Number(s):
PNNL-SA-80092
KC0201050; TRN: US201121%%343
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Volume: 47; Journal Issue: 33
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DIMENSIONS; CHEMISTRY; MATERIALS

Citation Formats

Shin, Sung M., Moon, Dohyun, Jeong, Kyung S., Kim, Jaheon, Thallapally, Praveen K., and Jeong, Nakcheol. Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing. United States: N. p., 2011. Web. doi:10.1039/C1CC12908B.
Shin, Sung M., Moon, Dohyun, Jeong, Kyung S., Kim, Jaheon, Thallapally, Praveen K., & Jeong, Nakcheol. Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing. United States. doi:10.1039/C1CC12908B.
Shin, Sung M., Moon, Dohyun, Jeong, Kyung S., Kim, Jaheon, Thallapally, Praveen K., and Jeong, Nakcheol. Wed . "Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing". United States. doi:10.1039/C1CC12908B.
@article{osti_1027176,
title = {Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing},
author = {Shin, Sung M. and Moon, Dohyun and Jeong, Kyung S. and Kim, Jaheon and Thallapally, Praveen K. and Jeong, Nakcheol},
abstractNote = {The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is dependent on the dimension of SBB's. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which can be added on the list of invariant rod packings.},
doi = {10.1039/C1CC12908B},
journal = {Chemical Communications},
number = 33,
volume = 47,
place = {United States},
year = {2011},
month = {7}
}