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Title: Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers

Abstract

Crystallisation of lower-rim tetra-O-alkylated p-carboxylatocalix[4]arenes from pyridine results in the formation of both bi-layer and pillar type supramolecular motifs. Full alkylation at the calixarene lower rim has significant influence over the supramolecular self-assembly motif, including preclusion of pyridine guest molecules from the calixarene cavity in the solid state.

Authors:
; ;
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
Advanced Light Source Division
OSTI Identifier:
1023372
Report Number(s):
LBNL-4692E
TRN: US201120%%958
DOE Contract Number:  
DE-AC02-05CH11231
Resource Type:
Journal Article
Resource Relation:
Journal Name: Dalton Transactions; Journal Volume: 39; Journal Issue: 2; Related Information: Journal Publication Date: 2009
Country of Publication:
United States
Language:
English
Subject:
37; ALKYLATION; CRYSTALLIZATION; CALIXARENES; ETHERS; MOLECULES; PYRIDINE; SOLIDS

Citation Formats

Kennedy, Stuart, Teat, Simon J., and Dalgarno, Scott J. Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers. United States: N. p., 2009. Web.
Kennedy, Stuart, Teat, Simon J., & Dalgarno, Scott J. Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers. United States.
Kennedy, Stuart, Teat, Simon J., and Dalgarno, Scott J. Wed . "Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers". United States. https://www.osti.gov/servlets/purl/1023372.
@article{osti_1023372,
title = {Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers},
author = {Kennedy, Stuart and Teat, Simon J. and Dalgarno, Scott J.},
abstractNote = {Crystallisation of lower-rim tetra-O-alkylated p-carboxylatocalix[4]arenes from pyridine results in the formation of both bi-layer and pillar type supramolecular motifs. Full alkylation at the calixarene lower rim has significant influence over the supramolecular self-assembly motif, including preclusion of pyridine guest molecules from the calixarene cavity in the solid state.},
doi = {},
journal = {Dalton Transactions},
number = 2,
volume = 39,
place = {United States},
year = {Wed Jul 08 00:00:00 EDT 2009},
month = {Wed Jul 08 00:00:00 EDT 2009}
}