A method for preparing sodium acrylate-d3, a useful and stable precursor for deuterated acrylic monomers
Journal Article
·
· Journal of Labelled Compounds and Radiopharmaceuticals
- ORNL
A convenient and economical method for converting propiolic acid to sodium acrylate-d3 is described. Successive D/H exchange of the alkyne proton of sodium propiolate (prepared from propiolic acid) using D2O affords sodium propiolate-d having up to 99 atom% D. Sodium propiolate-d can be partially reduced to sodium acrylate-d3 with 90% conversion and 89% yield, using D2 and the Lindlar catalyst with control of reaction parameters to maximize conversion while minimizing over reduction.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC05-00OR22725
- OSTI ID:
- 1023314
- Journal Information:
- Journal of Labelled Compounds and Radiopharmaceuticals, Vol. 54, Issue 12; ISSN 0362-4803
- Country of Publication:
- United States
- Language:
- English
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