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Title: Sputtering of tin and gallium-tin clusters

Abstract

Tin and gallium-tin clusters have been produced by 4 keV Ar{sup +} ion bombardment of polycrystalline tin and the gallium-tin eutectic alloy and analyzed by time-of-flight mass spectrometry. The sputtered neutral species were photoionized with 193 nm (6.4 eV) excimer laser light. Neutral tin clusters containing up to 10 atoms and mixed gallium-tin clusters Ga{sub (n-m)}Sn{sub m} with n {<=} 4 for the neutrals and N {<=} 3 for the sputtered ionic species have been detected. Laser power density dependent intensity measurements, relative yields, and kinetic energy distributions have been measured. The abundance distributions of the mixed clusters have been found to be nonstatistical due to significant differences in the ionization efficiencies for clusters with equal nuclearity but different number of tin atoms. The results indicate that Ga{sub 2}Sn and Ga{sub 3}Sn like the all-gallium clusters have ionization potentials below 6.4 eV. In the case of Sn{sub 5}, Sn{sub 6}, GaSn and Ga{sub (n-m)}Sn{sub m} clusters with n=2 to 4 and m>1, the authors detect species that have sufficient internal energy to be one photon ionized despite ionization potentials that are higher 6.4 eV. The tin atom signal that is detected can be attributed to photofragmentation of dimers for bothmore » sputtering from polycrystalline tin and from the gallium-tin eutectic alloy.« less

Authors:
; ; ;
Publication Date:
Research Org.:
Argonne National Lab., IL (United States). Chemical Technology Div.
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
10180069
Report Number(s):
ANL/CHM/CP-83910; CONF-9408150-1
ON: DE94018389; TRN: 94:018905
DOE Contract Number:
W-31109-ENG-38
Resource Type:
Technical Report
Resource Relation:
Conference: 10. international workshop of inelastic ion-surface collisions,Grand Targhee Resort, WY (United States),8-12 Aug 1994; Other Information: PBD: 1 Aug 1994
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; TIN; SPUTTERING; GALLIUM ALLOYS; TIN ALLOYS; ARGON IONS; COLLISIONS; SOLID CLUSTERS; EXPERIMENTAL DATA; MASS SPECTRA; TIME-OF-FLIGHT SPECTROMETERS; IONIZATION POTENTIAL; 665300; INTERACTIONS BETWEEN BEAMS AND CONDENSED MATTER

Citation Formats

Lill, T., Calaway, W.F., Ma, Z., and Pellin, M.J.. Sputtering of tin and gallium-tin clusters. United States: N. p., 1994. Web. doi:10.2172/10180069.
Lill, T., Calaway, W.F., Ma, Z., & Pellin, M.J.. Sputtering of tin and gallium-tin clusters. United States. doi:10.2172/10180069.
Lill, T., Calaway, W.F., Ma, Z., and Pellin, M.J.. Mon . "Sputtering of tin and gallium-tin clusters". United States. doi:10.2172/10180069. https://www.osti.gov/servlets/purl/10180069.
@article{osti_10180069,
title = {Sputtering of tin and gallium-tin clusters},
author = {Lill, T. and Calaway, W.F. and Ma, Z. and Pellin, M.J.},
abstractNote = {Tin and gallium-tin clusters have been produced by 4 keV Ar{sup +} ion bombardment of polycrystalline tin and the gallium-tin eutectic alloy and analyzed by time-of-flight mass spectrometry. The sputtered neutral species were photoionized with 193 nm (6.4 eV) excimer laser light. Neutral tin clusters containing up to 10 atoms and mixed gallium-tin clusters Ga{sub (n-m)}Sn{sub m} with n {<=} 4 for the neutrals and N {<=} 3 for the sputtered ionic species have been detected. Laser power density dependent intensity measurements, relative yields, and kinetic energy distributions have been measured. The abundance distributions of the mixed clusters have been found to be nonstatistical due to significant differences in the ionization efficiencies for clusters with equal nuclearity but different number of tin atoms. The results indicate that Ga{sub 2}Sn and Ga{sub 3}Sn like the all-gallium clusters have ionization potentials below 6.4 eV. In the case of Sn{sub 5}, Sn{sub 6}, GaSn and Ga{sub (n-m)}Sn{sub m} clusters with n=2 to 4 and m>1, the authors detect species that have sufficient internal energy to be one photon ionized despite ionization potentials that are higher 6.4 eV. The tin atom signal that is detected can be attributed to photofragmentation of dimers for both sputtering from polycrystalline tin and from the gallium-tin eutectic alloy.},
doi = {10.2172/10180069},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Aug 01 00:00:00 EDT 1994},
month = {Mon Aug 01 00:00:00 EDT 1994}
}

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