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Title: A modeling study of contaminant transport resulting from flooding of Pit 9 at the Radioactive Waste Management Complex, Idaho National Engineering Laboratory

Technical Report ·
DOI:https://doi.org/10.2172/10167003· OSTI ID:10167003

A simulation study was conducted to determine if dissolved-phase transport due to flooding is a viable mechanism for explaining the presence of radionuclides in sedimentary interbeds below the Radioactive Waste Management Complex. In particular, the study focused on {sup 241}Am migration due to flooding of Pit 9 in 1969. A kinetically-controlled source term model was used to estimate the mass of {sup 241}Am that leached as a function of a variable surface infiltration rate. This mass release rate was then used in a numerical simulation of unsaturated flow and transport to estimate the advance due to flooding of the {sup 241}Am front down towards the 110 ft interbed. The simulation included the effect of fractures by superimposing them onto elements that represented the basalt matrix. For the base case, hydraulic and transport parameters were assigned using the best available data. The advance of the {sup 241}Am front due to flooding for this case was minimal, on the order of a few meters. This was due to the strong tendency for {sup 241}Am to sorb onto both basalts and sediments. In addition to the base case simulation, a parametric sensitivity study was conducted which tested the effect of sorption in the fractures, in the kinetic source term, and in the basalt matrix. Of these, the only case which resulted in significant transport was when there was no sorption in the basalt matrix. The indication being that other processes such as transport by radiocolloids or organic complexation may have contributed. However, caution is advised in interpreting these results due to approximations in the numerical method that was used incorporate fractures into the simulation. The approximations are a result of fracture apertures being significantly smaller than the elements over which they are superimposed. The sensitivity of the {sup 241}Am advance to the assumed hydraulic conductivity for the fractures was also tested.

Research Organization:
EG and G Idaho, Inc., Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC07-76ID01570
OSTI ID:
10167003
Report Number(s):
EGG-EEL-10498; ON: DE93016668; TRN: 93:015538
Resource Relation:
Other Information: PBD: Sep 1992
Country of Publication:
United States
Language:
English