Synthesis of hydrogen-carbon clathrate material and hydrogen evolution therefrom at moderate temperatures and pressures

Lueking, Angela; Narayanan, Deepa

Synthesis of hydrogen-carbon clathrate material and hydrogen evolution therefrom at moderate temperatures and pressures

Patent · 07 March 2011

OSTI ID:1016545

Lueking, Angela ^[1]; Narayanan, Deepa ^[2]

State College, PA
Redmond, WA

A process for making a hydrogenated carbon material is provided which includes forming a mixture of a carbon source, particularly a carbonaceous material, and a hydrogen source. The mixture is reacted under reaction conditions such that hydrogen is generated and/or released from the hydrogen source, an amorphous diamond-like carbon is formed, and at least a portion of the generated and/or released hydrogen associates with the amorphous diamond-like carbon, thereby forming a hydrogenated carbon material. A hydrogenated carbon material including a hydrogen carbon clathrate is characterized by evolution of molecular hydrogen at room temperature at atmospheric pressure in particular embodiments of methods and compositions according to the present invention.

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Research Organization:: The Penn State Research Foundation (University Park, PA)

Sponsoring Organization:: USDOE

DOE Contract Number:: FC26-03NT41874

Assignee:: The Penn State Research Foundation (University Park, PA)

Patent Number(s):: 7,901,661

Application Number:: US Patent Application 11/613,999

OSTI ID:: 1016545

Country of Publication:: United States

Language:: English

References (21)

Study of the activation process of Mg-based hydrogen storage materials modified by graphite and other carbonaceous compounds Bouaricha, S.; Dodelet, J-P.; Guay, D. Journal of Materials Research, Vol. 16, Issue 10 https://doi.org/10.1557/JMR.2001.0398	journal	October 2001
Hydrogen desorption property of mechanically prepared nanostructured graphite Orimo, S.; Matsushima, T.; Fujii, H. Journal of Applied Physics, Vol. 90, Issue 3 https://doi.org/10.1063/1.1385362	journal	August 2001
Effect of carbon-containing compounds on the hydriding behavior of nanocrystalline Mg2Ni Bouaricha, S.; Dodelet, J. P.; Guay, D. Journal of Alloys and Compounds, Vol. 307, Issue 1-2 https://doi.org/10.1016/S0925-8388(00)00804-5	journal	July 2000
Characterization and hydriding properties of Mg-graphite composites prepared by mechanical grinding as new hydrogen storage materials Imamura, Hayao; Sakasai, Nozomu; Fujinaga, Tadatoshi Journal of Alloys and Compounds, Vol. 253-254 https://doi.org/10.1016/S0925-8388(96)03074-5	journal	May 1997
Enhanced hydrogen sorption capacities and kinetics of Mg ₂ Ni alloys by ball-milling with carbon and Pd coating Janot, R.; Aymard, L.; Rougier, A. Journal of Materials Research, Vol. 18, Issue 8 https://doi.org/10.1557/JMR.2003.0241	journal	August 2003
Preparation and hydriding properties of magnesium-containing hydrogen storage materials chemically deposited from a homogeneous phase Imamura, Hayao; Usui, Yoshihiro; Takashima, Masaharu Journal of the Less Common Metals, Vol. 175, Issue 1 https://doi.org/10.1016/0022-5088(91)90362-8	journal	September 1991
Hydriding–dehydriding behavior of magnesium composites obtained by mechanical grinding with graphite carbon Imamura, H. International Journal of Hydrogen Energy, Vol. 25, Issue 9 https://doi.org/10.1016/S0360-3199(99)00105-6	journal	September 2000
Hydrogen desorption from magnesium hydride–graphite nanocomposites produced by ball milling Dal Toè, S.; Lo Russo, S.; Maddalena, A. Materials Science and Engineering: B, Vol. 108, Issue 1-2 https://doi.org/10.1016/j.mseb.2003.10.030	journal	April 2004
Hydrogen storage composites obtained by mechanical grinding of magnesium with graphite carbon Imamura, Hayao; Takesue, Yoshirou; Tabata, Shinya Chemical Communications, Issue 22 https://doi.org/10.1039/a906454k	journal	January 1999
Structural observation of nano-structured and amorphous hydrogen storage materials by neutron diffraction Fukunaga, T.; Itoh, K.; Orimo, S. Materials Science and Engineering: B, Vol. 108, Issue 1-2 https://doi.org/10.1016/j.mseb.2003.10.059	journal	April 2004
Hydrogen in the mechanically prepared nanostructured graphite Orimo, S.; Majer, G.; Fukunaga, T. Applied Physics Letters, Vol. 75, Issue 20 https://doi.org/10.1063/1.125241	journal	November 1999
Hydrogen storage properties on mechanically milled graphite Ichikawa, T.; Chen, D. M.; Isobe, S. Materials Science and Engineering: B, Vol. 108, Issue 1-2 https://doi.org/10.1016/j.mseb.2003.10.094	journal	April 2004
Hydrogen sorption properties of graphite-modified magnesium nanocomposites prepared by ball-milling Bobet, J. -L.; Grigorova, E.; Khrussanova, M. Journal of Alloys and Compounds, Vol. 366, Issue 1-2 https://doi.org/10.1016/S0925-8388(03)00746-1	journal	March 2004
Research and Development of Mg-Based Hydrogen Storage Alloys for Intended Use in Nickel-Metal Hydride Batteries Iwakura, Chiaki; Inoue, Hiroshi; Furukawa, Naoji Electrochemistry, Vol. 71, Issue 9 https://doi.org/10.5796/electrochemistry.71.776	journal	January 2003
Composites for hydrogen storage by mechanical grinding of graphite carbon and magnesium Imamura, Hayao; Tabata, Shinya; Shigetomi, Noriko Journal of Alloys and Compounds, Vol. 330-332 https://doi.org/10.1016/S0925-8388(01)01506-7	journal	January 2002
Are carbon nanostructures an efficient hydrogen storage medium? Hirscher, Michael; Becher, Marion; Haluska, Miroslav Journal of Alloys and Compounds, Vol. 356-357, p. 433-437 https://doi.org/10.1016/S0925-8388(03)00142-7	journal	August 2003
Hydrogen storage in carbon nanostructures Hirscher, M.; Becher, M.; Haluska, M. Journal of Alloys and Compounds, Vol. 330-332 https://doi.org/10.1016/S0925-8388(01)01643-7	journal	January 2002
Analysis of the interface in graphite/magnesium composites at the nanometer scale Wu, Feng; Zhu, Jing; Ibe, K. Composites Science and Technology, Vol. 58, Issue 1 https://doi.org/10.1016/S0266-3538(97)00091-2	journal	January 1998
Hydrogen absorption of Mg-Based composites prepared by mechanical milling: Factors affecting its characteristics Imamura, Hayao; Sakasai, Nozomu; Kajii, Yasuyuki Journal of Alloys and Compounds, Vol. 232, Issue 1-2 https://doi.org/10.1016/0925-8388(95)01882-4	journal	January 1996
Hydriding Properties of Mg-Based Hydrogen Storage Materials Prepared Chemically from a Homogeneous Phase* Imamura, Hayao; Nakamura, Masahiro Zeitschrift für Physikalische Chemie, Vol. 183, Issue Part_1_2 https://doi.org/10.1524/zpch.1994.183.Part_1_2.157	journal	January 1994
Structural transformations in graphite induced by magneto-mechanical-milling in hydrogen atmosphere Smolira, A.; Szymanska, M.; Jartych, E. Journal of Alloys and Compounds, Vol. 402, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.04.154	journal	October 2005

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