Activated aluminum hydride hydrogen storage compositions and uses thereof

Sandrock, Gary; Reilly, James; Graetz, Jason; Wegrzyn, James E

Title: Activated aluminum hydride hydrogen storage compositions and uses thereof

Patent · Tue Nov 23 00:00:00 EST 2010

OSTI ID:1014767

Sandrock, Gary ^[1]; Reilly, James ^[2]; Graetz, Jason ^[3]; Wegrzyn, James E ^[4]

Ringwood, NJ
Bellport, NY
Mastic, NY
Brookhaven, NY

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-98CH10886

Assignee:: Brookhaven Science Associates, LLC (Upton, NY)

Patent Number(s):: 7,837,976

Application Number:: US Patent Application 11/192,262

OSTI ID:: 1014767

Country of Publication:: United States

Language:: English

References (13)

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Solid state phase transformations in LiAlH4 during high-energy ball-milling Balema, V. P.; Pecharsky, V. K.; Dennis, K. W. Journal of Alloys and Compounds, Vol. 313, Issue 1-2 https://doi.org/10.1016/S0925-8388(00)01201-9	journal	December 2000
Thermodynamic Properties of Aluminum Hydride Sinke, G. C.; Walker, L. C.; Oetting, F. L. The Journal of Chemical Physics, Vol. 47, Issue 8 https://doi.org/10.1063/1.1712294	journal	October 1967
The Chemistry of Complex Aluminohydrides Ashby, E. C. Advances in Inorganic Chemistry and Radiochemistry https://doi.org/10.1016/S0065-2792(08)60205-8	book	January 1966
Hydrogen cycling behavior of zirconium and titanium–zirconium-doped sodium aluminum hydride Zidan, Ragaiy A.; Takara, Satoshi; Hee, Allan G. Journal of Alloys and Compounds, Vol. 285, Issue 1-2, p. 119-122 https://doi.org/10.1016/S0925-8388(99)00006-7	journal	June 1999
Catalyzed Complex Metal Hydrides Bogdanović, Borislav; Sandrock, Gary MRS Bulletin, Vol. 27, Issue 9 https://doi.org/10.1557/mrs2002.227	journal	September 2002
A comparison of hydrogen, methanol and gasoline as fuels for fuel cell vehicles: implications for vehicle design and infrastructure development Ogden, Joan M.; Steinbugler, Margaret M.; Kreutz, Thomas G. Journal of Power Sources, Vol. 79, Issue 2 https://doi.org/10.1016/S0378-7753(99)00057-9	journal	June 1999
The Equilibrium Between Solid Aluminium Hydride and Gaseous Hydrogen Baranowski, B.; Tkacz, M. Zeitschrift für Physikalische Chemie, Vol. 135, Issue 135 https://doi.org/10.1524/zpch.1983.135.135.027	journal	January 1983
Accelerated thermal decomposition of AlH3 for hydrogen-fueled vehicles Sandrock, G.; Reilly, J.; Graetz, J. Applied Physics A, Vol. 80, Issue 4 https://doi.org/10.1007/s00339-004-3105-0	journal	February 2005
Advanced titanium doping of sodium aluminum hydride:: segue to a practical hydrogen storage material? Jensen, Craig M.; Zidan, Ragaiy; Mariels, Nathan International Journal of Hydrogen Energy, Vol. 24, Issue 5, p. 461-465 https://doi.org/10.1016/S0360-3199(98)00092-5	journal	May 1999
Crystal structure of aluminum hydride Turley, June W.; Rinn, Harold W. Inorganic Chemistry, Vol. 8, Issue 1 https://doi.org/10.1021/ic50071a005	journal	January 1969
Preparation and properties of aluminum hydride Brower, Frank M.; Matzek, Norman E.; Reigler, Paul F. Journal of the American Chemical Society, Vol. 98, Issue 9 https://doi.org/10.1021/ja00425a011	journal	April 1976
Rapid solid-state transformation of tetrahedral [AlH4]− into octahedral [AlH6]3− in lithium aluminohydride Balema, Viktor P.; Dennis, Kevin W.; Pecharsky, Vitalij K. Chemical Communications, Issue 17 https://doi.org/10.1039/b004144k	journal	January 2000

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