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Title: Multiheteromacrocycles that complex metal ions. Ninth progress report (includes results of last three years), 1 May 1980--30 April 1983

Abstract

The overall objective of this research is to design, synthesize, and evaluate cyclic and polycyclic host organic compounds for the abilities to complex and lipophilize guest metal ions, their complexes, and their clusters. Host organic compounds consist of strategically placed solvating, coordinating, and ion-pairing sites tied together by covalent bonds through hydrocarbon units around cavities shaped to be occupied by guest metal ions, or by metal ions plus their ligands. Specificity in complexation is sought by matching the following properties of host and guest: cavity and metal ion sizes; geometric arrangements of binding sites; numbers of binding sites; characters of binding sites; and valences. The hope is to synthesize new classes of compounds useful in the separation of metal ions, their complexes, and their clusters.

Authors:
Publication Date:
Research Org.:
California Univ., Los Angeles, CA (United States). Dept. of Chemistry
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
10120943
Report Number(s):
DOE/ER/72018-9
ON: DE92007472
DOE Contract Number:  
AS03-76ER72018
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 15 Sep 1982
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHELATING AGENTS; CHEMICAL PREPARATION; IONS; SEPARATION PROCESSES; PROGRESS REPORT; LIGANDS; POLYETHYLENE GLYCOLS; FREE ENTHALPY; 400201; 400105; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES; SEPARATION PROCEDURES

Citation Formats

Cram, D.J. Multiheteromacrocycles that complex metal ions. Ninth progress report (includes results of last three years), 1 May 1980--30 April 1983. United States: N. p., 1982. Web. doi:10.2172/10120943.
Cram, D.J. Multiheteromacrocycles that complex metal ions. Ninth progress report (includes results of last three years), 1 May 1980--30 April 1983. United States. doi:10.2172/10120943.
Cram, D.J. Wed . "Multiheteromacrocycles that complex metal ions. Ninth progress report (includes results of last three years), 1 May 1980--30 April 1983". United States. doi:10.2172/10120943. https://www.osti.gov/servlets/purl/10120943.
@article{osti_10120943,
title = {Multiheteromacrocycles that complex metal ions. Ninth progress report (includes results of last three years), 1 May 1980--30 April 1983},
author = {Cram, D.J.},
abstractNote = {The overall objective of this research is to design, synthesize, and evaluate cyclic and polycyclic host organic compounds for the abilities to complex and lipophilize guest metal ions, their complexes, and their clusters. Host organic compounds consist of strategically placed solvating, coordinating, and ion-pairing sites tied together by covalent bonds through hydrocarbon units around cavities shaped to be occupied by guest metal ions, or by metal ions plus their ligands. Specificity in complexation is sought by matching the following properties of host and guest: cavity and metal ion sizes; geometric arrangements of binding sites; numbers of binding sites; characters of binding sites; and valences. The hope is to synthesize new classes of compounds useful in the separation of metal ions, their complexes, and their clusters.},
doi = {10.2172/10120943},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Sep 15 00:00:00 EDT 1982},
month = {Wed Sep 15 00:00:00 EDT 1982}
}

Technical Report:

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