Removal of the compound layer from decanned Hanford uranium slugs by the use of sodium hydroxide
About twenty-five to thirty per cent of the uranium slugs canned in the Metal Preparation Section do not meet specifications and are rejected. These rejected slugs are recovered by a chemical process and prepared for re-canning. The canning operation provides a coating of metal composed principally of elemental aluminum and silicon with traces of copper and tin, which bonds the aluminum can to the slug. The elements in intimate contact with the slug combine chemically with the uranium to form the tenacious compound layer. The current recovery process consists essentially of a sodium hydroxide-sodium nitrate bath for chemically removing the aluminum can and the bonding medium, followed by hydrofluoric acid and nitric acid baths to remove the remaining compound layer and to pickle the slugs before they are returned to the process canning line. Recent studies have indicated the possibility of using a more economical means of recovery. This includes the mechanical removal of the aluminum can and most of the bonding medium, followed by a chemical removal of the residual compound layer by a solution of sodium hydroxide. A laboratory scale investigation was made to determine whether a solution of sodium hydroxide would remove the compound layer from de-canned, triple-dipped and lead-dipped uranium slugs. This document discusses the investigation and its conclusion.
- Research Organization:
- General Electric Co., Richland, WA (United States). Hanford Atomic Products Operation
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 10120819
- Report Number(s):
- HW-28282; ON: DE92007668
- Resource Relation:
- Other Information: PBD: 15 May 1953
- Country of Publication:
- United States
- Language:
- English
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