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Title: Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993

Abstract

The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. With a feed containing hydrogen and carbon monoxide in the molar ratio of 0.5 to 1.0 to the slurry bubble-column reactor, the catalyst performance target is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%. Contract tasks are as follows: 1.0: Catalyst development; 1.1--Technology assessment; 1.2--Precipitated catalyst preparation method development; 1.3--Novel catalyst preparation methods investigation; 1.4--Catalyst pretreatment; 1.5--Catalyst characterization; 2.0--Catalyst testing; 3.0--Catalyst aging studies, and 4.0--Preliminary design and cost estimate of a catalyst synthesis facility. This paper reports progress made on Task 1.2 and 2.0.

Authors:
;
Publication Date:
Research Org.:
UOP, Inc., Des Plaines, IL (United States)
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
10113209
Report Number(s):
DOE/PC/90055-T11
ON: DE94005030; BR: AA2520000; TRN: AHC29402%%24
DOE Contract Number:  
AC22-90PC90055
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: [1993]
Country of Publication:
United States
Language:
English
Subject:
01 COAL, LIGNITE, AND PEAT; FISCHER-TROPSCH SYNTHESIS; CATALYSTS; CHEMICAL PREPARATION; PERFORMANCE TESTING; PROGRESS REPORT; IRON OXIDES; COPPER OXIDES; POTASSIUM; CATALYTIC EFFECTS; EXPERIMENTAL DATA; 010408; C1 PROCESSES

Citation Formats

Frame, R R, and Gala, H B. Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993. United States: N. p., 1993. Web. doi:10.2172/10113209.
Frame, R R, & Gala, H B. Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993. United States. doi:10.2172/10113209.
Frame, R R, and Gala, H B. Fri . "Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993". United States. doi:10.2172/10113209. https://www.osti.gov/servlets/purl/10113209.
@article{osti_10113209,
title = {Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 10, December 26, 1992--March 26, 1993},
author = {Frame, R R and Gala, H B},
abstractNote = {The objectives of this contract are to develop a technology for the production of active and stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. With a feed containing hydrogen and carbon monoxide in the molar ratio of 0.5 to 1.0 to the slurry bubble-column reactor, the catalyst performance target is 88% CO + H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe. The desired sum of methane and ethane selectivities is no more than 4%, and the conversion loss per week is not to exceed 1%. Contract tasks are as follows: 1.0: Catalyst development; 1.1--Technology assessment; 1.2--Precipitated catalyst preparation method development; 1.3--Novel catalyst preparation methods investigation; 1.4--Catalyst pretreatment; 1.5--Catalyst characterization; 2.0--Catalyst testing; 3.0--Catalyst aging studies, and 4.0--Preliminary design and cost estimate of a catalyst synthesis facility. This paper reports progress made on Task 1.2 and 2.0.},
doi = {10.2172/10113209},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1993},
month = {12}
}