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Title: A materials compatibility study in FM-1, a liquid component of a paste extrudable explosive

Technical Report ·
DOI:https://doi.org/10.2172/10102836· OSTI ID:10102836
; ;  [1];  [2]
  1. Sandia National Labs., Livermore, CA (United States)
  2. Mason and Hanger-Silas Mason Co., Inc., Amarillo, TX (United States). Pantex Plant

The chemical compatibility of various metallic and organic containment materials with a constituent of a paste extrudable explosive (PEX) has been examined through a series of long-term exposures. Corrosion coupons and mechanical test specimens (polymers only) were exposed to FM-1, a principal liquid component of PEX, at 74{degree}C. RX-08-FK is the LLNL designator for this formulation. Compatibility was determined by measuring changes in weight, physical dimensions, and mechanical properties, by examining the coupons for discoloration, surface attack, and corrosion products, and by analyzing for dissolved metals in the FM-1. Of the metals and alloys examined, none of the 300 series stainless steels exhibited adequate corrosion resistance after 74 days of exposure. Copper showed evidence of severe uniform surface attack. Monel 400 also exhibited signs of chemical attack. Nickel and tantalum showed less evidence of attack, although neither, was immune to the liquid. Gold coupons developed a ``tarnish`` film. The gold along with an aluminum alloy, 6061 (in the T6 condition) performed the most satisfactorily. A wide range of polymers were tested for 61 days at 74{degree}C. The materials that exhibited the most favorable response in terms of weight change, dimensional stability, and mechanical properties were Kalrez, PTFE Teflon, and polyethylene.

Research Organization:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC04-76DR00789
OSTI ID:
10102836
Report Number(s):
SAND-93-8237; ON: DE94001166
Resource Relation:
Other Information: PBD: Sep 1993
Country of Publication:
United States
Language:
English