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Title: Resonant inelastic X-ray scattering (RIXS) spectroscopy at the Mn K absorption pre-edgea direct probe of the 3d orbitals

Abstract

A study of the Mn K absorption pre-edges in oxides using resonant inelastic X-ray scattering (RIXS) spectroscopy is presented. The energy transfer dimension enhances the separation of the pre-edge (predominantly 1s to 3d transitions) from the main K-edge and a detailed analysis is thus possible. The RIXS spectra are sensitive to the Mn spin state. The technique thus yields detailed information on the electronic structure that is not accessible in conventional K-edge absorption spectroscopy. The line splittings can be understood within a ligand field multiplet model, showing the importance of (2p,3d) two-electron interactions that give rise to the spin-sensitivity.

Authors:
; ; ; ; ; ; ;  [1]
  1. UCD
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1008654
Resource Type:
Journal Article
Journal Name:
J. Phys. Chem. Solids
Additional Journal Information:
Journal Volume: 66; Journal Issue: (12) ; 2005
Country of Publication:
United States
Language:
ENGLISH
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ABSORPTION SPECTROSCOPY; CRYSTAL FIELD; DIMENSIONS; ELECTRONIC STRUCTURE; ENERGY TRANSFER; INORGANIC COMPOUNDS; K ABSORPTION; MULTIPLETS; OXIDES; PROBES; SCATTERING; SPECTRA; SPECTROSCOPY; SPIN

Citation Formats

Glatzel, Pieter, Yano, Junko, Bergmann, Uwe, Visser, Hendrik, Robblee, John H, Gu, Weiwei, de Groot, Frank M.F., Cramer, Stephen P, Yachandra, Vittal K, SSRL), Utrecht), ESRF), and LBNL). Resonant inelastic X-ray scattering (RIXS) spectroscopy at the Mn K absorption pre-edgea direct probe of the 3d orbitals. United States: N. p., 2010. Web.
Glatzel, Pieter, Yano, Junko, Bergmann, Uwe, Visser, Hendrik, Robblee, John H, Gu, Weiwei, de Groot, Frank M.F., Cramer, Stephen P, Yachandra, Vittal K, SSRL), Utrecht), ESRF), & LBNL). Resonant inelastic X-ray scattering (RIXS) spectroscopy at the Mn K absorption pre-edgea direct probe of the 3d orbitals. United States.
Glatzel, Pieter, Yano, Junko, Bergmann, Uwe, Visser, Hendrik, Robblee, John H, Gu, Weiwei, de Groot, Frank M.F., Cramer, Stephen P, Yachandra, Vittal K, SSRL), Utrecht), ESRF), and LBNL). Mon . "Resonant inelastic X-ray scattering (RIXS) spectroscopy at the Mn K absorption pre-edgea direct probe of the 3d orbitals". United States.
@article{osti_1008654,
title = {Resonant inelastic X-ray scattering (RIXS) spectroscopy at the Mn K absorption pre-edgea direct probe of the 3d orbitals},
author = {Glatzel, Pieter and Yano, Junko and Bergmann, Uwe and Visser, Hendrik and Robblee, John H and Gu, Weiwei and de Groot, Frank M.F. and Cramer, Stephen P and Yachandra, Vittal K and SSRL) and Utrecht) and ESRF) and LBNL)},
abstractNote = {A study of the Mn K absorption pre-edges in oxides using resonant inelastic X-ray scattering (RIXS) spectroscopy is presented. The energy transfer dimension enhances the separation of the pre-edge (predominantly 1s to 3d transitions) from the main K-edge and a detailed analysis is thus possible. The RIXS spectra are sensitive to the Mn spin state. The technique thus yields detailed information on the electronic structure that is not accessible in conventional K-edge absorption spectroscopy. The line splittings can be understood within a ligand field multiplet model, showing the importance of (2p,3d) two-electron interactions that give rise to the spin-sensitivity.},
doi = {},
url = {https://www.osti.gov/biblio/1008654}, journal = {J. Phys. Chem. Solids},
number = (12) ; 2005,
volume = 66,
place = {United States},
year = {2010},
month = {7}
}