skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis and Structural Characterization of Lithium-Based Metal−Organic Frameworks

Abstract

Two lithium-based metal-organic frameworks, Li{sub 2}(C{sub 14}H{sub 8}O{sub 4}) [Li{sub 2}(4,4'-BPDC) [1]; ULMOF-2, UL = ultralight; BPDC = biphenyldicarboxylate]; space group P2{sub 1}/c, a = 12.758(2) {angstrom}, b = 5.142(4) {angstrom}, c = 8.00(2) {angstrom}, {beta} = 97.23{sup o}, V = 520.6(14) {angstrom}{sup 3} and Li{sub 2}(C{sub 14}H{sub 8}O{sub 6}S) [Li{sub 2}(4,4'-SDB) [2]; ULMOF-3, UL = ultralight; SDB = sulfonyldibenzoate], space group P2{sub 1}/n, a = 5.5480(11) {angstrom}, b = 23.450(5) {angstrom}, c = 10.320(2) {angstrom}, {beta} = 96.47(3){sup o}, V = 1334.1(5) {angstrom}3, were synthesized. Compounds 1 and 2 were synthesized by solvothermal methods and were characterized using single crystal X-ray diffraction. Structure 1 consists of layers of two-dimensional antifluorite related LiO motif connected by BPDC linkers, whereas structure 2 is constructed by a combination of tetrameric lithium polyhedral clusters connected by the sulfonyldibenzoate linker. The frameworks are stable up to 575 and 500 C, respectively, under N{sub 2} atmosphere.

Authors:
; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1005989
Resource Type:
Journal Article
Journal Name:
Cryst. Growth Des.
Additional Journal Information:
Journal Volume: 9; Journal Issue: (11) ; 11, 2009
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; LITHIUM COMPOUNDS; ORGANOMETALLIC COMPOUNDS; MONOCRYSTALS; SYNTHESIS; X-RAY DIFFRACTION; CRYSTAL STRUCTURE

Citation Formats

Banerjee, Debasis, Borkowski, Lauren A, Kim, Sun Jin, Parise, John B, IST-Korea), and SBU). Synthesis and Structural Characterization of Lithium-Based Metal−Organic Frameworks. United States: N. p., 2009. Web. doi:10.1021/cg900705c.
Banerjee, Debasis, Borkowski, Lauren A, Kim, Sun Jin, Parise, John B, IST-Korea), & SBU). Synthesis and Structural Characterization of Lithium-Based Metal−Organic Frameworks. United States. doi:10.1021/cg900705c.
Banerjee, Debasis, Borkowski, Lauren A, Kim, Sun Jin, Parise, John B, IST-Korea), and SBU). Tue . "Synthesis and Structural Characterization of Lithium-Based Metal−Organic Frameworks". United States. doi:10.1021/cg900705c.
@article{osti_1005989,
title = {Synthesis and Structural Characterization of Lithium-Based Metal−Organic Frameworks},
author = {Banerjee, Debasis and Borkowski, Lauren A and Kim, Sun Jin and Parise, John B and IST-Korea) and SBU)},
abstractNote = {Two lithium-based metal-organic frameworks, Li{sub 2}(C{sub 14}H{sub 8}O{sub 4}) [Li{sub 2}(4,4'-BPDC) [1]; ULMOF-2, UL = ultralight; BPDC = biphenyldicarboxylate]; space group P2{sub 1}/c, a = 12.758(2) {angstrom}, b = 5.142(4) {angstrom}, c = 8.00(2) {angstrom}, {beta} = 97.23{sup o}, V = 520.6(14) {angstrom}{sup 3} and Li{sub 2}(C{sub 14}H{sub 8}O{sub 6}S) [Li{sub 2}(4,4'-SDB) [2]; ULMOF-3, UL = ultralight; SDB = sulfonyldibenzoate], space group P2{sub 1}/n, a = 5.5480(11) {angstrom}, b = 23.450(5) {angstrom}, c = 10.320(2) {angstrom}, {beta} = 96.47(3){sup o}, V = 1334.1(5) {angstrom}3, were synthesized. Compounds 1 and 2 were synthesized by solvothermal methods and were characterized using single crystal X-ray diffraction. Structure 1 consists of layers of two-dimensional antifluorite related LiO motif connected by BPDC linkers, whereas structure 2 is constructed by a combination of tetrameric lithium polyhedral clusters connected by the sulfonyldibenzoate linker. The frameworks are stable up to 575 and 500 C, respectively, under N{sub 2} atmosphere.},
doi = {10.1021/cg900705c},
journal = {Cryst. Growth Des.},
number = (11) ; 11, 2009,
volume = 9,
place = {United States},
year = {2009},
month = {12}
}