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Title: Detection of Indentation Induced FE-to-AFE Phase Transformation in Lead Zirconate Titanate

Abstract

Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 {micro}m were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.

Authors:
 [1];  [1];  [1];  [2];  [2];  [3];  [3]
  1. ORNL
  2. Drexel University
  3. Sandia National Laboratories (SNL)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Center for Nanophase Materials Sciences
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1003712
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of the American Chemical Society; Journal Volume: 89; Journal Issue: 11
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; CERAMICS; DETECTION; DIAMONDS; MICROSCOPY; PHASE TRANSFORMATIONS; PZT; RAMAN SPECTROSCOPY; SPECTROSCOPY

Citation Formats

Baddorf, Arthur P, Kalinin, Sergei V, Shin, Junsoo, Juliano, Thomas F., Gogotsi, Yury G., Buchheit, Thomas E., and Watson, Chad S. Detection of Indentation Induced FE-to-AFE Phase Transformation in Lead Zirconate Titanate. United States: N. p., 2006. Web.
Baddorf, Arthur P, Kalinin, Sergei V, Shin, Junsoo, Juliano, Thomas F., Gogotsi, Yury G., Buchheit, Thomas E., & Watson, Chad S. Detection of Indentation Induced FE-to-AFE Phase Transformation in Lead Zirconate Titanate. United States.
Baddorf, Arthur P, Kalinin, Sergei V, Shin, Junsoo, Juliano, Thomas F., Gogotsi, Yury G., Buchheit, Thomas E., and Watson, Chad S. Sun . "Detection of Indentation Induced FE-to-AFE Phase Transformation in Lead Zirconate Titanate". United States. doi:.
@article{osti_1003712,
title = {Detection of Indentation Induced FE-to-AFE Phase Transformation in Lead Zirconate Titanate},
author = {Baddorf, Arthur P and Kalinin, Sergei V and Shin, Junsoo and Juliano, Thomas F. and Gogotsi, Yury G. and Buchheit, Thomas E. and Watson, Chad S.},
abstractNote = {Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 {micro}m were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.},
doi = {},
journal = {Journal of the American Chemical Society},
number = 11,
volume = 89,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 2006},
month = {Sun Jan 01 00:00:00 EST 2006}
}