Hindered Diphenoquinones: Diradicals of Oxygen
Attempts were made to prepare a diphenoquinone having substituents in 2,2'-positions in order to prevent the planarity of the molecule and get a diradical of oxygen. The 2,2'-dimethyl-5,5'-di-t-butyldiphenoquinone was prepared and was shown to be in equilibrium with a small amount of diradical. This compound slowly polymerizes.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USAEC
- DOE Contract Number:
- DE-AC02-05CH11231
- OSTI ID:
- 915453
- Report Number(s):
- UCRL-3466; TRN: US200817%%361
- Country of Publication:
- United States
- Language:
- English
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