Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction
The objective of this project is to identify, prepare, test, characterize, and evaluate a practical, homogeneous catalyst for a water-gas shift process. The project effort is divided into the following five tasks: (1) Update SRI's recent review of the literature on the catalysis of the water-gas shift reaction (WGSR) to include references after 1982 and those in the patent literature. Based on this review, SRI will choose ten candidate systems to be evaluated as to their abilities to catalyze the WGSR using syngas derived from gasified coal. (2) Develop a test plan designed to effectively evaluate both the catalysts and, to some extent, reactor configuration for WGSR catalysis. (3) Perform a series of experiments to identify the most effective and economical of the ten candidate catalysts and then further evaluate the reaction kinetics of at least one selected catalyst system to develop sufficient data to provide the basis for the work in Task 4. (4) Develop a mathematical model of the final candidate system that uses rate expressions to describe the catalytic process. (5) Perform a techno-economical evaluation of the catalyst in terms of a proposed plant design based on the reaction model, current costs, and standard chemical engineering practice and compare the proposed design with a conventional hydrogen plant.
- Research Organization:
- SRI International, Menlo Park, CA (United States)
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC21-85MC22065
- OSTI ID:
- 7205415
- Report Number(s):
- DOE/MC/22065-T15; ON: DE92017716
- Country of Publication:
- United States
- Language:
- English
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Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction
Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction. Task 1, Topical report No. 1