Combustion of a solid particle. [Mathematical models]
We consider the quasi-steady burning of a carbon particle which undergoes gasification at its surface by chemical reactions, followed by a homogeneous reaction in the gas phase. The burning rate M is found as a function of the gas phase Damkoehler number D/sub g/ for the whole range o < D/sub g/ < infinity. The monotonic M(D/sub g/) curve, obtained for relatively very hot or very cold particles, describes the gradual transition from frozen flow to equilibrium. For moderate particle temperatures the transition is abrupt and the M(D/sub g/) curve is either S-shaped or Z-shaped. In the former the burning is enhanced at ignition while in the latter it is slowed down; this depends on the relative importance of the two competitive surface reactions. At extinction, the reverse is true: burning is slowed down in the case of an S curve and is enhanced in the case of a Z curve.
- Research Organization:
- Polytechnic Inst. of New York, Farmingdale (USA); Northwestern Univ., Evanston, IL (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC01-78ET11056
- OSTI ID:
- 6715335
- Report Number(s):
- DOE/ET/11056-T2
- Country of Publication:
- United States
- Language:
- English
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ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
01 COAL, LIGNITE, AND PEAT
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CHEMICAL REACTIONS
GASIFICATION
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ELEMENTS
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NONMETALS
OXIDATION
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