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Title: Combustion of a solid particle. [Mathematical models]

Technical Report ·
DOI:https://doi.org/10.2172/6715335· OSTI ID:6715335

We consider the quasi-steady burning of a carbon particle which undergoes gasification at its surface by chemical reactions, followed by a homogeneous reaction in the gas phase. The burning rate M is found as a function of the gas phase Damkoehler number D/sub g/ for the whole range o < D/sub g/ < infinity. The monotonic M(D/sub g/) curve, obtained for relatively very hot or very cold particles, describes the gradual transition from frozen flow to equilibrium. For moderate particle temperatures the transition is abrupt and the M(D/sub g/) curve is either S-shaped or Z-shaped. In the former the burning is enhanced at ignition while in the latter it is slowed down; this depends on the relative importance of the two competitive surface reactions. At extinction, the reverse is true: burning is slowed down in the case of an S curve and is enhanced in the case of a Z curve.

Research Organization:
Polytechnic Inst. of New York, Farmingdale (USA); Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC01-78ET11056
OSTI ID:
6715335
Report Number(s):
DOE/ET/11056-T2
Country of Publication:
United States
Language:
English