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Title: Electrocatalyst-support interactions

Abstract

The maximum utilization of noble metals as heterogeneous catalysts is achieved by dispersing the noble metals as small particles supported on a porous, high surface area powder. In some studies with supported noble metal catalysts, it has been reported that the metal particle interacts with the support material and that the interaction affects the catalytic properties of the metal. Experimental studies on metal-support interactions that are pertinent to electrocatalysis will be discussed. Platinum supported on carbon black is one of the most active electrocatalysts for oxygen reduction in phosphoric acid fuel cells. In the acid environment at 100 to 200/sup 0/C, the Pt surface area decreases with time due to the growth of the supported Pt particles. The effects of a liquid-phase environment on the particle growth mechanism of supported Pt catalysts is discussed. 60 references.

Authors:
Publication Date:
Research Org.:
Argonne National Lab., IL (USA)
OSTI Identifier:
6538287
Report Number(s):
CONF-7805100-1
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Conference
Resource Relation:
Conference: Workshop on the electrocatalysis of fuel cell reactions, Upton, NY, USA, 15 May 1978
Country of Publication:
United States
Language:
English
Subject:
30 DIRECT ENERGY CONVERSION; ACID ELECTROLYTE FUEL CELLS; CATALYSTS; SINTERING; PLATINUM; CARBON BLACK; CATALYSIS; CATALYTIC EFFECTS; CATHODES; CHEMICAL REACTIONS; ELECTRIC CONDUCTIVITY; GOLD; OXYGEN; PHOSPHORIC ACID; REDUCTION; SILVER; SUBSTRATES; SUPPORTS; TRANSITION ELEMENTS; CARBON; CRYOGENIC FLUIDS; DIRECT ENERGY CONVERTERS; ELECTRICAL PROPERTIES; ELECTROCHEMICAL CELLS; ELECTRODES; ELEMENTS; FABRICATION; FLUIDS; FUEL CELLS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; MECHANICAL STRUCTURES; METALS; NONMETALS; PHYSICAL PROPERTIES; PLATINUM METALS; 300503* - Fuel Cells- Materials, Components, & Auxiliaries

Citation Formats

Kinoshita, K. Electrocatalyst-support interactions. United States: N. p., 1978. Web.
Kinoshita, K. Electrocatalyst-support interactions. United States.
Kinoshita, K. 1978. "Electrocatalyst-support interactions". United States. https://www.osti.gov/servlets/purl/6538287.
@article{osti_6538287,
title = {Electrocatalyst-support interactions},
author = {Kinoshita, K.},
abstractNote = {The maximum utilization of noble metals as heterogeneous catalysts is achieved by dispersing the noble metals as small particles supported on a porous, high surface area powder. In some studies with supported noble metal catalysts, it has been reported that the metal particle interacts with the support material and that the interaction affects the catalytic properties of the metal. Experimental studies on metal-support interactions that are pertinent to electrocatalysis will be discussed. Platinum supported on carbon black is one of the most active electrocatalysts for oxygen reduction in phosphoric acid fuel cells. In the acid environment at 100 to 200/sup 0/C, the Pt surface area decreases with time due to the growth of the supported Pt particles. The effects of a liquid-phase environment on the particle growth mechanism of supported Pt catalysts is discussed. 60 references.},
doi = {},
url = {https://www.osti.gov/biblio/6538287}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1978},
month = {Sun Jan 01 00:00:00 EST 1978}
}

Conference:
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