Conducting hybrid polymeric systems
The studies took advantage of the opportunities offered by copolymerization for gaining insight into electrical conduction, morphology, phase separation, polymer-polymer interfaces, and solubility. Copolymerization is technologically important for it allows one to tailor-make products with specifically desired properties. However, the utility of copolymerization involving conjugated, rigid components could be different from that of conventional polymers. This paper is focused on the synthesis and properties of various materials: Rod-coil systems such as polyisoprene/polyacetylene diblock copolymers (resonance raman and small angle neutron scattering studies correlated to conductivity); and alternating copolymers such as poly (arylpyrroles) (electrochemical synthesis and characterization). 8 refs., 4 figs.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Australian National Univ., Canberra, ACT (Australia)
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 6046000
- Report Number(s):
- LA-UR-87-3048; CONF-8709138-2; ON: DE88000527
- Resource Relation:
- Conference: 1. European polymer symposium, Lyon, France, 14 Sep 1987; Other Information: Portions of this document are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
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COPOLYMERS
ELECTRIC CONDUCTIVITY
MORPHOLOGY
POLYACETYLENES
ABSORPTION SPECTRA
COPOLYMERIZATION
DOPED MATERIALS
INTERFACES
OPTICAL PROPERTIES
PHASE STUDIES
POLYISOPRENE
POLYMERIZATION
PYRROLES
RAMAN SPECTRA
SMALL ANGLE SCATTERING
SOLUBILITY
SYNTHESIS
AZOLES
CHEMICAL REACTIONS
ELASTOMERS
ELECTRICAL PROPERTIES
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
MATERIALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
PHYSICAL PROPERTIES
POLYENES
POLYMERS
SCATTERING
SPECTRA
360603* - Materials- Properties