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Title: Alternative process schemes for coal conversion. Progress report No. 1, October 1, 1978--January 31, 1979

Technical Report ·
DOI:https://doi.org/10.2172/6020287· OSTI ID:6020287

On the basis of simple, first approximation calculations, it has been shown that catalytic gasification and hydrogasification are inherently superior to conventional gasification with respect to carbon utilization and thermal efficiency. However, most processes which are directed toward the production of substitute natural gas (SNG) by direct combination of coal with steam at low temperatures (catalytic processes) or with hydrogen (hydrogasification) will require a step for separation of product SNG from a recycle stream. The success or falure of the process could well depend upon the economics of this separation scheme. The energetics for the separation of mixtures of ideal gases has been considered in some detail. Minimum energies for complete separation of representative effluent mixtures have been calculated as well as energies for separation into product and recycle streams. The gas mixtures include binary systems of H/sub 2/ and CH/sub 4/ and ternary mixtures of H/sub 2/, CH/sub 4/, and CO. A brief summary of a number of different real separation schemes has also been included. We have arbitrarily divided these into five categories: liquefaction, absorption, adsorption, chemical, and diffusional methods. These separation methods will be screened and the more promising methods examined in more detail in later reports. Finally, a brief mention of alternative coal conversion processes concludes this report.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
DOE Contract Number:
EY-76-C-02-0016
OSTI ID:
6020287
Report Number(s):
BNL-51011
Country of Publication:
United States
Language:
English