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Title: Ion exchange and adsorption on low rank coals for liquefaction

Technical Report ·
DOI:https://doi.org/10.2172/10179944· OSTI ID:10179944

The objectives of this program are to study the application of catalysts and the catalysis of liquefaction of low rank coals. Ion exchange and adsorption techniques are being used or modified to incorporate catalytically active metals (Fe, Co, Ni and Mo) in relatively small (100-2000 ppM) quantities into coal samples. Relative oil yields are being determined by PETC and Auburn University workers as collaborators to establish the effectiveness of the catalyst incorporation techniques. It is hoped that these techniques will provide highly active forms of the catalyst in low concentrations to minimize the need for metals recovery. A two step preparation of the coal is used to (1) remove material which both limits oil conversion and prepares for the addition of exchangeable catalyst, and (2) add catalytically active material which enhances the conversion of the coal matter to the oil fraction in the processing.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
10179944
Report Number(s):
ANL/CHM/CP-83909; CONF-9409168-3; ON: DE94018394
Resource Relation:
Conference: Coal liquefaction and gas conversion contractors` review conference,Pittsburgh, PA (United States),7-8 Sep 1994; Other Information: PBD: [1994]
Country of Publication:
United States
Language:
English