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Title: Evaluation of etchants for deoxidizing aluminum components

Technical Report ·
DOI:https://doi.org/10.2172/10125921· OSTI ID:10125921

In the canning operation, the preparation of aluminum components is important in assuring uniform wetting of the aluminum surfaces with Al-Si. The surfaces of the components should be free of dirt and grease and should also have a minimum retention of non-metallic film, normally aluminum oxide, for the best wetting properties. At present, dirt and grease are removed satisfactorily by a vapor degreaser followed by a Duponol-alkaline wash. The standard specified method of removing the aluminum oxide film from aluminum cans is a four-minute etch in twenty percent phosphoric acid. The oxide is removed from the caps by an eight-minute etch in twenty per cent phosphoric acid or an alternate etch of a one percent solution of hydrofluosilicic acid. If the phosphoric acid etch is not controlled properly, it is possible to form a thin, inert phosphate coating on the surface of the aluminum, which is undesirable for good wetting characteristics. In an effort to find a better etchant for aluminum components, an investigation of various commercial and non-commercial etchants was undertaken. This report details results of this investigation.

Research Organization:
Hanford Site (HNF), Richland, WA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
10125921
Report Number(s):
HW-27734; HAN-53803; ON: DE94006954
Resource Relation:
Other Information: PBD: 15 Apr 1953
Country of Publication:
United States
Language:
English