The gas-phase thermal chemistry of tetralin and related model systems
- Iowa State Univ., Ames, IA (United States)
The thesis is divided into 5 papers: gas-phase thermal decomposition of tetralin; flash vacuum pyrolysis of 3-benzocycloheptenone and 1,3, 4,5-tetrahydro-2-benzothiepin-2,2-dioxide (model systems for gas-phase pyrolysis of tetralin); high-temperature gas-phase reactions of o-allylbenzyl radicals generated by flash vacuum pyrolysis of is(o-allylbenzyl) oxalate; flash vacuum pyrolysis of 1,4-diphenylbutane; and flash vacuum pyrolysis of o-allyltoluene, o-(3-butenyl)toluene and o-(pentenyl)toluene were also used.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 10115289
- Report Number(s):
- IS-T-1616; ON: DE94005277
- Resource Relation:
- Other Information: TH: Thesis (Ph.D.); PBD: May 1993
- Country of Publication:
- United States
- Language:
- English
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Pyrolysis of 9-methylenespiro(3. 5)nona-5,7-diene: A route to benzo-2-hexene-1,6-diyl, a putative intermediate in the retro-Diels-Alder reaction of tetralin
Thesis/Dissertation
·
Fri Feb 10 00:00:00 EST 1995
·
OSTI ID:10115289
Gas-phase intramolecular Diels-Alder reactions of 2,3-dimethylene-2,3-dihydrofurans. II. Formation of anthracene and other polycyclic aromatic compounds in the pyrolysis of 1,5-bidenzocyclooctadienes and related compounds. III. Formation of 9-methylanthracene and anthracene in the pyrolysis of 5,6,11,12-tetrahydrodibenzo(A,E)cyclooctene and other related compounds. IV. Preparation of cyclopentadienones by flash vacuum pyrolysis and their dimerization and intramolecular reactions
Thesis/Dissertation
·
Thu Jan 01 00:00:00 EST 1987
·
OSTI ID:10115289
Pyrolysis of 9-methylenespiro(3. 5)nona-5,7-diene: A route to benzo-2-hexene-1,6-diyl, a putative intermediate in the retro-Diels-Alder reaction of tetralin
Journal Article
·
Fri Jul 20 00:00:00 EDT 1990
· Journal of Organic Chemistry; (United States)
·
OSTI ID:10115289