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Title: Molecular shock response of explosives: electronic absorption spectroscopy

Conference ·
DOI:https://doi.org/10.1063/1.3295046· OSTI ID:991256

Electronic absorption spectroscopy in the range 400-800 nm was coupled to ultrafast laser generated shocks to begin addressing the question of the extent to which electronic excitations are involved in shock induced reactions. Data are presented on shocked polymethylmethacrylate (PMMA) thin films and single crystal pentaerythritol tetranitrate (PETN). Shocked PMMA exhibited thin film interference effects from the shock front. Shocked PETN exhibited interference from the shock front as well as broadband increased absorption. Relation to shock initiation hypotheses and the need for time dependent absorption data (future experiments) is briefly discussed.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-06NA25396
OSTI ID:
991256
Report Number(s):
LA-UR-09-04797; LA-UR-09-4797; TRN: US201021%%134
Resource Relation:
Conference: APS Shock Compression of Condensed Matter ; June 29, 2009 ; Nashville, TN, USA
Country of Publication:
United States
Language:
English