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Title: RESULTS OF PHYSICOCHEMICAL CHARACTERIZATION AND CAUSTIC DISSOLUTION TESTS ON TANK 241-C-108 HEEL SOLIDS

Technical Report ·
DOI:https://doi.org/10.2172/983929· OSTI ID:983929

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

Research Organization:
Hanford Site (HNF), Richland, WA (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Environmental Management (EM)
DOE Contract Number:
DE-AC27-08RV14800
OSTI ID:
983929
Report Number(s):
LAB-RPT-10-00001 Rev 0; TRN: US1005265
Country of Publication:
United States
Language:
English