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Title: EVIDENCE OF CORROSIVE GAS FORMED BY RADIOLYSIS OF CHLORIDE SALTS IN PLUTONIUM-BEARING MATERIALS

Journal Article · · JOURNAL OF NUCLEAR MATERIALS MANAGEMENT
OSTI ID:978435

Corrosion and pitting have been observed in headspace regions of stainless steel containers enclosing plutonium oxide/salt mixtures. These observations are consistent with the formation of a corrosive gas, probably HCl, and transport of that gas to the headspace regions of sealed containers. The NH{sub 4}Cl films found on the walls of the sealed containers is also indicative of the presence of HCl gas. Radiolysis of hydrated alkaline earth salts is the probable source of HCl.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
DE-AC09-08SR22470
OSTI ID:
978435
Report Number(s):
SRNL-STI-2010-00051; TRN: US201010%%96
Journal Information:
JOURNAL OF NUCLEAR MATERIALS MANAGEMENT, Journal Name: JOURNAL OF NUCLEAR MATERIALS MANAGEMENT
Country of Publication:
United States
Language:
English