Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties
Abstract
Ultraviolet light is known to be one of the most efficient methods to initiatc polymeric reactions in the presence of a photonitiator. Photopolymerizations are advantageous because the chemistry of the materials can be tailored to design liquid monomers for ultrarapid polymerization into a solid polymer material. One way to achieve rapid photopolymerizations is to utilize multifunctional (meth)acrylate monomers. which form highly crosslinked polymers; however, these monomers typically do not achieve complete functional group conversion. Recently, Decker et al. developed novel monovinyl acrylate monomers that display polyriicrization kinetics that rival those of multifunctional acrylate monomers. These novel acrylate monomers incorporate secondary functionalities and end groups such as carbonates, carbamates, cyclic carbonates and oxazolidone which promote the increased polymerization kinetics of these monomers. In addition to thc polynierization kinetics, these novel monovinyl monomers form crosslinked polymers, which are characterized by having high strength and high flexibility. Unfortunately, the exact mechanism or mechanisms responsible for the polymerization kinetics and crosslinking are not well understood.
- Authors:
-
- Eric R.
- Kathryn A.
- Jun
- Hui
- Jeffrey W.
- Christopher N.
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 976485
- Report Number(s):
- LA-UR-02-7597
TRN: US201017%%634
- Resource Type:
- Conference
- Resource Relation:
- Conference: Submitted to: Division of Polymer Chemistry (preprint), ACS National Meeting 2003, March 23-27, 2003, New Orleans, Louisiana
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACRYLATES; CARBAMATES; CARBONATES; CHEMISTRY; DESIGN; FLEXIBILITY; FUNCTIONALS; KINETICS; MONOMERS; POLYMERIZATION; POLYMERS
Citation Formats
Beckel, E R, Berchtold, K A, Nie, J, Lu, H, Stansbury, J W, and Bowman, C N. Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties. United States: N. p., 2002.
Web.
Beckel, E R, Berchtold, K A, Nie, J, Lu, H, Stansbury, J W, & Bowman, C N. Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties. United States.
Beckel, E R, Berchtold, K A, Nie, J, Lu, H, Stansbury, J W, and Bowman, C N. 2002.
"Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties". United States. https://www.osti.gov/servlets/purl/976485.
@article{osti_976485,
title = {Novel (meth)acrylate monomers for ultrarapid polymerization and enhanced polymer properties},
author = {Beckel, E R and Berchtold, K A and Nie, J and Lu, H and Stansbury, J W and Bowman, C N},
abstractNote = {Ultraviolet light is known to be one of the most efficient methods to initiatc polymeric reactions in the presence of a photonitiator. Photopolymerizations are advantageous because the chemistry of the materials can be tailored to design liquid monomers for ultrarapid polymerization into a solid polymer material. One way to achieve rapid photopolymerizations is to utilize multifunctional (meth)acrylate monomers. which form highly crosslinked polymers; however, these monomers typically do not achieve complete functional group conversion. Recently, Decker et al. developed novel monovinyl acrylate monomers that display polyriicrization kinetics that rival those of multifunctional acrylate monomers. These novel acrylate monomers incorporate secondary functionalities and end groups such as carbonates, carbamates, cyclic carbonates and oxazolidone which promote the increased polymerization kinetics of these monomers. In addition to thc polynierization kinetics, these novel monovinyl monomers form crosslinked polymers, which are characterized by having high strength and high flexibility. Unfortunately, the exact mechanism or mechanisms responsible for the polymerization kinetics and crosslinking are not well understood.},
doi = {},
url = {https://www.osti.gov/biblio/976485},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 2002},
month = {Tue Jan 01 00:00:00 EST 2002}
}