Gas generation over plutonium oxides in the 94-1 shelf-life surveillance program.
- John M.
- David M.
- Dallas D.
- Dennis D.
- Douglas Kirk
- Laura A.
The Department of Energy (DOE) is embarking upon a program to store large quantities of plutonium-bearing materials for up to fifty years. The Los Alamos National Laboratory Shelf Life Project was established to bound the behavior of plutonium-bearing material meeting the DOE 3013 Standard. The shelf life study monitors temperature, pressure and gas composition over oxide materials in a limited number of large-scale 3013 inner containers and in many small-scale containers. For the large-scale study, baseline plutonium oxides, oxides exposed to high-humidity atmospheres, and oxides containing chloride salt impurities are planned. The first large-scale container represents a baseline and contains dry plutonium oxide prepared according to the 3013 Standard. This container has been observed for pressure, temperature and gas compositional changes for less than a year. Results indicate that no detectable changes in pressure and gas composition are observed.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 976287
- Report Number(s):
- LA-UR-02-5102; TRN: US1006866
- Resource Relation:
- Conference: Submitted to: American Nuclear Society Fifth Topical Meeting for Spent Nuclear Fuel and Fissile Materials Management, Sept. 17-20, 2002, Charleston, SC
- Country of Publication:
- United States
- Language:
- English
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