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Title: Exploitation of resonance Raman spectroscopy as a remote chemical sensor

Conference ·
OSTI ID:97212

We have discussed recent experimental results using a resonance-Raman-based LIDAR system as a remote chemical sensor. This spectroscopy has the fundamental advantage that it is based on optical fingerprints that are insensitive to environmental perturbations. By taking advantage of resonance enhancement, which 6 orders-of-magnitude, can be as large as 4 to an increased sensing range for a given chemical concentration or lower detection limit for a given stand-off distance can be realized. The success discussed above can in part be traced back to the use of new state-of-the-art technologies which, only recently, have allowed the phenomenon of resonance-enhanced Raman spectroscopy to be fully exploited as a remote chemical sensor platform. Since many chemicals have electronic transitions in the UV/IS, it is expected that many will have pronounced resonance enhancements.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC02-76CH00016
OSTI ID:
97212
Report Number(s):
BNL-61359; CONF-950787-35; ON: DE95016012
Resource Relation:
Conference: 36. annual meeting of the Institute for Nuclear Materials Management, Palm Desert, CA (United States), 9-12 Jul 1995; Other Information: PBD: [1995]
Country of Publication:
United States
Language:
English