Project Work Plan Chromium Vadose Zone Characterization and Geochemistry
The major objectives of the proposed study are to 1) determine the leaching characteristics of Cr(VI) from contaminated sediments collected from 100 area spill sites, 2) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford site 100 areas through the use of i) macroscopic solubility studies and ii) microscale characterization of contaminated sediments, and 3) from these data construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 area vadose zone. These objectives are based on locating and obtaining contaminated sediment with depth and at varying Cr(VI) concentrations as we hypothesize that mineral/chemical-Cr(VI) associations should be related to the total Cr concentration and other master geochemical variables (e.g., pH, counter-cation type and concentration, and water content). In addressing these objectives, additional benefits accrued will be (1) a fuller understanding of Cr(VI) entrained in the vadose zone that will that can be utilized in modeling potential Cr(VI) source terms, and 2) accelerating the Columbia River 100 area corridor cleanup by developing remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 944519
- Report Number(s):
- PNNL-SA-50254; TRN: US200902%%913
- Country of Publication:
- United States
- Language:
- English
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