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Title: Compositional tuning of ferromagnetism in Ga1-xMnxP

Abstract

We report the magnetic and transport properties of Ga{sub 1-x}Mn{sub x}P synthesized via ion implantation followed by pulsed laser melting over a range of x, namely 0.018 to 0.042. Like Ga{sub 1-x}Mn{sub x}As, Ga{sub 1-x}Mn{sub x}P displays a monotonic increase of the ferromagnetic Curie temperature with x associated with the hole-mediated ferromagnetic phase while thermal annealing above 300 C leads to a quenching of ferromagnetism that is accompanied by a reduction of the substitutional fraction of Mn. However, contrary to observations in Ga{sub 1-x}Mn{sub x}As, Ga{sub 1-x}Mn{sub x}P is non-metallic over the entire composition range. At the lower temperatures over which the films are ferromagnetic, hole transport occurs via hopping conduction in a Mn-derived band; at higher temperatures it arises from holes in the valence band which are thermally excited across an energy gap that shrinks with x.

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Director. Office of Science. Basic EnergySciences
OSTI Identifier:
918811
Report Number(s):
LBNL-61577
Journal ID: ISSN 0038-1098; SSCOA4; R&D Project: 513390; BnR: KC0201030; TRN: US200819%%456
DOE Contract Number:  
DE-AC02-05CH11231
Resource Type:
Journal Article
Journal Name:
Solid State Communications
Additional Journal Information:
Journal Volume: 140; Related Information: Journal Publication Date: 2006; Journal ID: ISSN 0038-1098
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ANNEALING; CURIE POINT; ENERGY GAP; FERROMAGNETISM; ION IMPLANTATION; LASERS; MELTING; QUENCHING; TRANSPORT; TUNING; VALENCE

Citation Formats

Farshchi, R, Scarpulla, M A, Stone, P R, Yu, K M, Sharp, I D, Beeman, J W, Silvestri, H H, Reichertz, L A, Haller, E E, and Dubon, O D. Compositional tuning of ferromagnetism in Ga1-xMnxP. United States: N. p., 2006. Web. doi:10.1016/j.ssc.2006.09.010.
Farshchi, R, Scarpulla, M A, Stone, P R, Yu, K M, Sharp, I D, Beeman, J W, Silvestri, H H, Reichertz, L A, Haller, E E, & Dubon, O D. Compositional tuning of ferromagnetism in Ga1-xMnxP. United States. https://doi.org/10.1016/j.ssc.2006.09.010
Farshchi, R, Scarpulla, M A, Stone, P R, Yu, K M, Sharp, I D, Beeman, J W, Silvestri, H H, Reichertz, L A, Haller, E E, and Dubon, O D. 2006. "Compositional tuning of ferromagnetism in Ga1-xMnxP". United States. https://doi.org/10.1016/j.ssc.2006.09.010. https://www.osti.gov/servlets/purl/918811.
@article{osti_918811,
title = {Compositional tuning of ferromagnetism in Ga1-xMnxP},
author = {Farshchi, R and Scarpulla, M A and Stone, P R and Yu, K M and Sharp, I D and Beeman, J W and Silvestri, H H and Reichertz, L A and Haller, E E and Dubon, O D},
abstractNote = {We report the magnetic and transport properties of Ga{sub 1-x}Mn{sub x}P synthesized via ion implantation followed by pulsed laser melting over a range of x, namely 0.018 to 0.042. Like Ga{sub 1-x}Mn{sub x}As, Ga{sub 1-x}Mn{sub x}P displays a monotonic increase of the ferromagnetic Curie temperature with x associated with the hole-mediated ferromagnetic phase while thermal annealing above 300 C leads to a quenching of ferromagnetism that is accompanied by a reduction of the substitutional fraction of Mn. However, contrary to observations in Ga{sub 1-x}Mn{sub x}As, Ga{sub 1-x}Mn{sub x}P is non-metallic over the entire composition range. At the lower temperatures over which the films are ferromagnetic, hole transport occurs via hopping conduction in a Mn-derived band; at higher temperatures it arises from holes in the valence band which are thermally excited across an energy gap that shrinks with x.},
doi = {10.1016/j.ssc.2006.09.010},
url = {https://www.osti.gov/biblio/918811}, journal = {Solid State Communications},
issn = {0038-1098},
number = ,
volume = 140,
place = {United States},
year = {Tue May 23 00:00:00 EDT 2006},
month = {Tue May 23 00:00:00 EDT 2006}
}