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Title: Tailoring nanocrystalline diamond film properties

Patent ·
OSTI ID:913005

A method for controlling the crystallite size and growth rate of plasma-deposited diamond films. A plasma is established at a pressure in excess of about 55 Torr with controlled concentrations of hydrogen up to about 98% by volume, of unsubstituted hydrocarbons up to about 3% by volume and an inert gas of one or more of the noble gases and nitrogen up to about 98% by volume. The volume ratio of inert gas to hydrogen is preferably maintained at greater than about 4, to deposit a diamond film on a suitable substrate. The diamond film is deposited with a predetermined crystallite size and at a predetermined growth rate.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-31109-ENG-38
Assignee:
The University of Chicago (Chicago, IL)
Patent Number(s):
6,592,839
Application Number:
09/255,919
OSTI ID:
913005
Country of Publication:
United States
Language:
English

References (1)

Effects of noble gases on diamond deposition from methane‐hydrogen microwave plasmas journal August 1990

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