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Title: Measurement and Control of Glass Feedstocks

Technical Report ·
DOI:https://doi.org/10.2172/902660· OSTI ID:902660

ERCo has developed a laser-based technology for rapid compositional measurements of batch, real-time sorting of cullet, and in-situ measurements of molten glass. This technology, termed LIBS (Laser Induced Breakdown Spectroscopy) can determine whether or not the batch was formulated accurately in order to control glass quality. It can also be used to determine if individual batch ingredients are within specifications. In the case of cullet feedstocks, the sensor can serve as part of a system to sort cullet by color and ensure that it is free of contaminants. In-situ compositional measurements of molten glass are achieved through immersing a LIBS probe directly into the melt in a glass furnace. This technology has been successfully demonstrated in ERCo’s LIBS laboratory for batch analysis, cullet sorting, and glass melt measurements. A commercial batch analyzer has been operating in a PPG fiberglass plant since August 2004. LIBS utilizes a highly concentrated laser pulse to rapidly vaporize and ionize nanograms of the material being studied. As this vapor cools, it radiates light at specific wavelengths corresponding to the elemental constituents (e.g. silicon, aluminum, iron) of the material. The strengths of the emissions correlate to the concentrations of each of the elemental constituents. By collecting the radiated light with a spectrometer capable of resolving and measuring these wavelengths, the elemental composition of the sample is found.

Research Organization:
Energy Research Compnay, 2571-A Arthur Kill Road, Staten Island, NY 10309
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
FC36-01ID14030
OSTI ID:
902660
Report Number(s):
DOE ID14030; TRN: US200722%%329
Country of Publication:
United States
Language:
English