FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE
Abstract
Fractional crystallization is being considered as a pretreatment method to support supplemental treatment of retrieved single-shell tank (SST) saltcake waste at the Hanford Site. The goal of the fractional crystallization process is to optimize the separation of the radioactivity (radionuclides) from the saltcake waste and send it to the Waste Treatment and Immobilization Plant and send the bulk of the saltcake to the supplemental treatment plant (bulk vitrification). The primary factors that influence the separation efficiency are (1) solid/liquid separation efficiency, (2) contaminant inclusions, and (3) co-precipitation. This is a report of testing for factors (2) and (3) with actual tank waste samples. For the purposes of this report, contaminant inclusions are defined as the inclusion of supernatant, containing contaminating radionuclides, in a pocket within the precipitating saltcake crystals. Co-precipitation is defined as the simultaneous precipitation of a saltcake crystal with a contaminating radionuclide. These two factors were tested for various potential fractional crystallization product salts by spiking the composite tank waste samples (SST Early or SST Late, external letter CH2M-0600248, ''Preparation of Composite Tank Waste Samples for ME-21 Project'') with the desired target salt and then evaporating to precipitate that salt. SST Early represents the typical composition of dissolvedmore »
- Authors:
- Publication Date:
- Research Org.:
- Hanford Site (HNF), Richland, WA (United States)
- Sponsoring Org.:
- USDOE - Office of Environmental Management (EM)
- OSTI Identifier:
- 896712
- Report Number(s):
- RPP-RPT-31998 Rev 0
TRN: US0700836
- DOE Contract Number:
- DE-AC27-99RL14047
- Resource Type:
- Technical Report
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; COPRECIPITATION; CRYSTALLIZATION; EFFICIENCY; PRECIPITATION; RADIOACTIVITY; RADIOISOTOPES; TANKS; TARGETS; TESTING; VITRIFICATION; WASTE PROCESSING; WASTES
Citation Formats
WARRANT, R W. FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE. United States: N. p., 2006.
Web. doi:10.2172/896712.
WARRANT, R W. FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE. United States. https://doi.org/10.2172/896712
WARRANT, R W. 2006.
"FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE". United States. https://doi.org/10.2172/896712. https://www.osti.gov/servlets/purl/896712.
@article{osti_896712,
title = {FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE},
author = {WARRANT, R W},
abstractNote = {Fractional crystallization is being considered as a pretreatment method to support supplemental treatment of retrieved single-shell tank (SST) saltcake waste at the Hanford Site. The goal of the fractional crystallization process is to optimize the separation of the radioactivity (radionuclides) from the saltcake waste and send it to the Waste Treatment and Immobilization Plant and send the bulk of the saltcake to the supplemental treatment plant (bulk vitrification). The primary factors that influence the separation efficiency are (1) solid/liquid separation efficiency, (2) contaminant inclusions, and (3) co-precipitation. This is a report of testing for factors (2) and (3) with actual tank waste samples. For the purposes of this report, contaminant inclusions are defined as the inclusion of supernatant, containing contaminating radionuclides, in a pocket within the precipitating saltcake crystals. Co-precipitation is defined as the simultaneous precipitation of a saltcake crystal with a contaminating radionuclide. These two factors were tested for various potential fractional crystallization product salts by spiking the composite tank waste samples (SST Early or SST Late, external letter CH2M-0600248, ''Preparation of Composite Tank Waste Samples for ME-21 Project'') with the desired target salt and then evaporating to precipitate that salt. SST Early represents the typical composition of dissolved saltcake early in the retrieval process, and SST Late represents the typical composition during the later stages of retrieval.},
doi = {10.2172/896712},
url = {https://www.osti.gov/biblio/896712},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Dec 11 00:00:00 EST 2006},
month = {Mon Dec 11 00:00:00 EST 2006}
}