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Title: Mixed oxide solid solutions

Patent ·
OSTI ID:875058

The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
DOE Contract Number:
W-7405-ENG-48
Assignee:
Catalytica Energy Systems, Inc. (Mountain View, CA)
Patent Number(s):
US 6521566
OSTI ID:
875058
Country of Publication:
United States
Language:
English

References (6)

Preparation and properties of niobia- and tantala-doped orthorhombic zirconia journal January 1995
Compound and solid-solution formation, phase equilibria and electrical properties in the ceramic system ZrO 2 –La 2 O 3 –Ta 2 O 5 journal January 1991
Phases in the Zr x Ta 1 –x (O,N)y system, formed by ammonolysis of Zr–Ta gels: preparation of a baddeleyite-type solid solution phase Zr x Ta 1 –x O 1 +x N 1 –x , 0≤X≤1 journal January 1994
Zirconia as a support for catalysts Influence of additives on the thermal stability of the porous texture of monoclinic zirconia journal April 1991
Non-porous stabilized ZrO2 particles as support for catalysts journal January 1987
V2O5, Nb2O5 and Ta2O5 doped zirconia ceramics journal January 1994