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Title: Glass-ceramic material and method of making

Patent ·
OSTI ID:874641

The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC06-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
6,430,966
OSTI ID:
874641
Country of Publication:
United States
Language:
English

References (4)

Stacking of Planar SOFCs journal January 1995
The Stability of the Sealing GLASS AF 45 in H2/H2O - and O2/N2 - Atmospheres journal January 1997
Glass-ceramic sealants for solid oxide fuel cells: Part I. Physical properties journal June 1996
Glass-Ceramics Sealants in CaO-Al2O3-SiO2 System journal January 1997