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Title: Method for improving the durability of ion insertion materials

Patent ·
OSTI ID:874581

The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.

Research Organization:
Midwest Research Institute, Kansas City, MO (United States)
DOE Contract Number:
AC36-99GO10337
Assignee:
Midwest Research Institute (Kansas City, MO)
Patent Number(s):
US 6420071
OSTI ID:
874581
Country of Publication:
United States
Language:
English

References (4)

Preparation, Mechanical Properties, and Electrochemical Characterization of Polymer Gel Electrolytes Prepared from Poly(alkylene oxide) Macromonomers journal May 1999
All-Solid-State Rocking Chair Lithium Battery on a Flexible Al Substrate journal January 1999
Electrochromic materials and devices for energy efficient windows journal October 1984
Sol-Gel Lithium Silicate Electrolyte Thin Films journal January 1994