Palladium (II) catalyized polymerization of norbornene and acrylates

Sen, Ayusman; Kacker, Smita; Hennis, April; Polley, Jennifer D

Title: Palladium (II) catalyized polymerization of norbornene and acrylates

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Abstract

Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: [(L)Pd(R)(X)].sub.2, where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.

Inventors:

Sen, Ayusman ^[1]; Kacker, Smita ^[2]; Hennis, April ^[1]; Polley, Jennifer D ^[3]

State College, PA
Annandale, NJ
Exton, PA

Publication Date:: Tue Aug 29 00:00:00 EDT 2000

OSTI Identifier:: 873203

Patent Number(s):: US 6111041

Application Number:: 09/099,070

Assignee:: Penn State Research Foundation (University Park, PA)

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: palladium; ii; catalyized; polymerization; norbornene; acrylates; homopolymers; copolymers; norbornenes; prepared; contacting; acrylate; monomer; reactant; conditions; presence; solvent; catalyst; consisting; essentially; pd; dimer; component; formula; monodentate; phosphorus; nitrogen; ligand; anionic; alkyl; aryl; consisting essentially; /526/

Citation Formats


                    Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. Palladium (II) catalyized polymerization of norbornene and acrylates.  United States: N. p., 2000. 
        Web.

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                    Sen, Ayusman, Kacker, Smita, Hennis, April, & Polley, Jennifer D. Palladium (II) catalyized polymerization of norbornene and acrylates.  United States.

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                    Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. 2000.  
        "Palladium (II) catalyized polymerization of norbornene and acrylates".  United States.  https://www.osti.gov/servlets/purl/873203.

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@article{osti_873203,

  title        = {Palladium (II) catalyized polymerization of norbornene and acrylates},

  author       = {Sen, Ayusman and Kacker, Smita and Hennis, April and Polley, Jennifer D},

  abstractNote = {Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: [(L)Pd(R)(X)].sub.2, where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/873203},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Aug 29 00:00:00 EDT 2000},

  month        = {Tue Aug 29 00:00:00 EDT 2000}

}

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