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Title: Process for restoring membrane permeation properties

Patent ·
OSTI ID:870956

A process for restoring the selectivity of high-flee-volume, glassy polymer membranes for condensable components over less-condensable components or non-condensable components of a gas mixture. The process involves exposing the membrane to suitable sorbent vapor, such as propane or butane, thereby reopening the microvoids that make up the free volume. The selectivity of an aged membrane may be restored to 70-100% of its original value. The selectivity of a membrane which is known to age over time can also be maintained by keeping the membrane in a vapor environment when it is not in use.

Research Organization:
Membrane Technology & Res Inc
Sponsoring Organization:
USDOE
DOE Contract Number:
FG03-90ER81066; FG03-94ER81811
Assignee:
Membrane Technology and Research, Inc. (Menlo Park, CA)
Patent Number(s):
US 5630970
Application Number:
08/448652
OSTI ID:
870956
Country of Publication:
United States
Language:
English

References (2)

Transport characteristics and other physicochemical properties of aged poly(1-(trimethylsilyl)-1-;propyne) journal June 1993
Polyacetylene derivatives as membranes for gas separation journal March 1988