Process for reducing organic compounds with calcium, amine, and alcohol
Abstract
Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.
- Inventors:
- Publication Date:
- Research Org.:
- Purdue Univ., West Lafayette, IN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 865547
- Patent Number(s):
- 4,533,760
- Application Number:
- 06/643,649
- Assignee:
- Purdue Research Foundation (West Lafayette, IN)
- DOE Contract Number:
- AC02-81ER10989
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1984 Aug 23
- Country of Publication:
- United States
- Language:
- English
- Subject:
- /999/585/
Citation Formats
Benkeser, Robert A., Laugal, James A., and Rappa, Angela. Process for reducing organic compounds with calcium, amine, and alcohol. United States: N. p., 1985.
Web.
Benkeser, Robert A., Laugal, James A., & Rappa, Angela. Process for reducing organic compounds with calcium, amine, and alcohol. United States.
Benkeser, Robert A., Laugal, James A., and Rappa, Angela. 1985.
"Process for reducing organic compounds with calcium, amine, and alcohol". United States. https://www.osti.gov/servlets/purl/865547.
@article{osti_865547,
title = {Process for reducing organic compounds with calcium, amine, and alcohol},
author = {Benkeser, Robert A. and Laugal, James A. and Rappa, Angela},
abstractNote = {Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.},
doi = {},
url = {https://www.osti.gov/biblio/865547},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1985},
month = {Tue Jan 01 00:00:00 EST 1985}
}
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